For which of the following complexes are isomers possible? Explain how possible isomers for the following molecules changes if the molecule is square planar vs. tetrahedral. Draw the isomers if possible [Cr(ox)(NH3)2]* [PtF(OH2)(NO2)2]!

Q: For which of the following octahedral complexes are isomers possible? Draw all the isomers. a)…

A: Since you have asked a question with multiple sub-parts we will solve the first 3 subparts for you.…

Q: Why are low spin tetrahedral complexes not formed?

A: The division of d-orbitals present in central metal ion in sets of two different energies occur in…

Q: Illustrate the concepts of Transition-Metal Complexes?

A: Transition metal complexes are also named as coordination compounds. These complexes involve ions of…

Q: /hich of the following complex ions absorbs light of the shortest wavelength? A) [Crl6]3- B)…

A:

Q: Two Fe (II) complexes are both low spin but have different ligands. A solution of the other is red.…

A: The stronger the field, the greater the separation (in energy) between the split levels.  Electrons…

Q: How many different formulas are there for octahedral complexes with a metal M and four ligands A, B,…

A: The complexes in which the central metal atom is surrounded by six ligands are called an octahedral…

Q: Which ions are unlikely to form colored coordination complexes in an octahedral ligand environment?…

A: Colour for the complex is arise due to electronic transition. If no any transition possible compound…

Q: use crystal field theory to predict the number of unpaired electrons in the complexes and show…

A:

Q: <p>The complexes of Fe^3+ have magnetic properties that depend on whether the ligands are…

A: Iron, Fe has electronic configuration [Ar]4s23d6.  Hence, during the formation of Fe3+ ions, the…

Q: The complex [Co(ox)(PMe,), (NH,)Ci] shows total number of isomers is ... A) 5 В) 4 С) 3 D) 2

A:

Q: Which of the following octahedral complexes can form cis/trans isomers? Select one or more: a.…

A:

Q: If trans-[Cr(en)2(NCS)2]SCN is heated, it forms gaseousethylenediamine and solid…

A: The reaction on heating of the coordination compound trans-[Cr(en)2(NCS)2]SCN leads to the formation…

Q: Which of the following statements is true?     Cis-trans and mer-fac isomers are examples of…

A: A coordination complex consists of a central metal atom that is surrounded by bounded molecules…

Q: Which of the complexes or complex ions has geometric (cis or trans) isomers? 1) [Cr(NH3)5Cl]2+ 2)…

A: The complexes which shows cis and trans isomer are either Octahedral or having square planar…

Q: Which of the following complexes has an optical isomer?(a) Tetrahedral [CdBr2Cl2]2- (b) Octahedral…

A: The optical isomers are the non superimposable mirror images of each other. The compounds whose…

Q: Name the following metal complexes or complex ions: formula name [FeCi, (co).]

A: Complex ion consist of metal and several ligand within the coordination sphere Here we are required…

Q: Determine if each of the following metal complexes is chiral and therefore has an optical isomer:…

A: a.

Q: Which of the following ions could exist as either a low-spin or a high-sp octahedral complex…

A:

Q: (a) If a complex absorbs light at 610 nm, what color wouldyou expect the complex to be? (b) What is…

A: (a)

Q: Which of the following statements is TRUE about the complex, diaquabis(oxalato)ruthenate(II)? The…

A: The given coordination compound is diaquabis(oxalato)ruthenate(II).  First of we write the chemical…

Q: How many unpaired electrons are there in a high-spin octahedral Fe2+ complex? A diagram will likely…

A: Octahedral Fe2+ complex:

Q: 4) What is the shape of the complex ion? 5) Are the ligands strong or weak? 6) Is the compound high…

A:

Q: Consider the [Cu(H2O)6](NO3)2 complex. Which ONE of the following statements is FALSE? a.The…

A: Incorrect statement is complex has low-spin configuration

Q: why do some d-block elements form colored complexes with various ligands

A: in complexes of the transition metals the D orbitals do not all have the same energy. the pattern of…

Q: Which of the following complexes has the highest oxidation state of metal? a. Cr(n6-C6H6)2 b.…

A: a) (η6-C6H6)2Cr Let the oxidation state of Cr= x The oxidation state of η6-C6H6 =0 Overall charge on…

Q: How is Ao defined for octahedral transition metal complexes?

A:

Q: Consider the following three complexes. [Co(NH3)5SCN]2+ [Co(NH3)3Cl3]2+ 5NH3 Which of the…

A: In geometric isomerism is a type of stereoisomerism in which the atoms are arranged in a different…

Q: In the di-cationic complex (+2) shown below, how many electrons around the metal center can be…

A: For these type of questions, we must know about the valence electrons of metal and electrons…

Q: Explain why most zinc and silver complexes are colorless. Zinc and silver both have only one common…

A:

Q: How many unpaired electrons are there in the complex ion [CO(NO3)5]¯? For this in the nitrate…

A: Given , Initial amount of substance = 60mg  t1/2 = 6 h  Total time = 24 h  N ❓  In question 2  Since…

Q: Which cation is expected to give the greatest k value in an octahedral complex? * Fe2+ Ru2+ Os2+ O…

A:

Q: For the following transition metal complexes match the complex with its corresponding number of d…

A: The electronic configuration with the corresponding number of d electrons and low spin / high spin…

Q: How many isomers are possible for a tetrahedral complex [MA2BC]? а. О b b. 2 a с. 4

A: The number of isomers in tetrahedral complex having formula MA2BC are calculated as follows,

Q: 1. The two complexes are known to have octahedral geometry. The first complex is that Co*3 ion is…

A: The hybridization of a coordination compound can be be known from the electronic configuration of…

Q: Name the following metal complexes or complex ions: formula name [Fe(OH), (en); ] [v(eN), (NH,).]…

A:

Q: Draw the structures of optical isomers of each of the following complex ions:[Cr(C2O4)3]3-,…

A: Compounds which are non-super imposable mirror image of each other are known as optical isomers.

Q: Cobalt(II) forms more tetrahedral complexes than any other ion except zinc(II). Draw the…

A: The structure of the tetrahedral complex [CoCl2(en)] is

Q: What is the possible number of isomers of the OsO4py complex? A. 4 B. 1 C. 2 D. 5 E. 3

A: NOTE : The correct formula of the complex will be OsO4(py)2 and not OsO4py. Hence I'm considering…

Q: Q4/ geometrical isomerism is found in square planar and octahedral complexes but not found in…

A: Bidentate ligands are those in which two domor atoms are present. Ligands are those which attached…

Q: Answer the following questions about the transition metals complexes with the chemical formulas…

A: Compounds given with Chemical Formula [Co(en)3]3+  [CoCl6]3-

Q: In the following list, identify a transition metal cation that cannot be used to distinguish between…

A: To identify a transition metal cation that cannot be used to distinguish between strong-field and…

Q: In the below coordination compound, the sodium ions are A._______the hydroxide ions are counterions…

A:

Q: The complex ion [Co(CO3)3]3-, an octahedral complex with bidentate carbonate ions as ligands, has…

A: (a)

Q: Which of the following complexes could indicate the geometric isomer? (78Pt, 30Zn, 29Cu, 27Co) A.…

A: Complex compound show geometric isomers exist in cisvand trans form.

Q: Which of these complex ions is expected to be diamagnetic?           (B) [Co(CN)6]3–          (A)…

A: The nature of compound depends on the nature of ligand attached to the central atom. If the ligand…

Q: What kind of isomerism can the following complexes have? [Cd(NH3)2Cl4]SO4 , and [Mn(H2O)2(NH3)3OH]+

A: The exchange of the ions without changing the identity of a complex molecule is called Ionization…

Q: An octahedral complex, MA4B2 (A and B are monodentate ligands), has two stereoisomers (trans and…

A: The correct option is as follows:

Q: [NİCI2(PPH3)2] is paramagnetic while [PtCl2(PPH3)2] is diamagnetic, what are the possible structures…

A: Though Ni(II) and Pt (II) are both d8 system, Ni complex is tetrahedral, whereas Pt complex is…

Q: Name the following metal complexes or complex ions: formula name [re(co),]* [cr{OH),(en).]"

A: 1. Tetracarbonyl iron(III)

Q: Which of the following ions could exist as either a low-spin or a high-spin octahedral complex…

A: High spin complexes are formed with weak field ligands and low spin complexes are formed with strong…

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.