Given the MS spectra below, show the fragmentation pattern responsible for m/z values Relative abundance 100- 50 20 40 60 m/z 80 86 (M - CH₂)+ (CH3CH₂)2N M+ 101 100 120 P

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.27P: Following is the mass spectrum of an unknown compound. The two highest peaks are at m/z 120 and 122....
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Given the MS spectra below, show the fragmentation pattern responsible for m/z values
Relative abundance
100
50
0
20
40
60
m/z
80
86 (M - CH₂)+
(CH3CH₂)3N
M+•
101
100
120
P
Transcribed Image Text:Given the MS spectra below, show the fragmentation pattern responsible for m/z values Relative abundance 100 50 0 20 40 60 m/z 80 86 (M - CH₂)+ (CH3CH₂)3N M+• 101 100 120 P
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