H2. Pd 25° C, 3atm e) Reaction type Stereochemical Relationship Mechanism: H20, H2SO4 f) Reaction type Stereochemical Relationship Mechanism:

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter14: Elimination
Section: Chapter Questions
Problem 40CTQ
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H2. Pd
e)
25° C, 3atm
Reaction type
Stereochemical
Relationship
Mechanism:
H20, H2SO4
f)
"ph
Reaction type
Stereochemical
Relationship
Mechanism:
Transcribed Image Text:H2. Pd e) 25° C, 3atm Reaction type Stereochemical Relationship Mechanism: H20, H2SO4 f) "ph Reaction type Stereochemical Relationship Mechanism:
5) For the following reactions:
a. Complete the reactions with both possible chiral products.
b. Determine and label the absolute configuration (R or S) of all stereocenters.
c. Label the reaction type and the stereochemical relationship (meso, enantiomer, diastereomer, or none).
d. Draw out the reaction mechanism showing lone pairs, arrows, bond making/breaking, etc. for each
reaction.
CH
(R)
CH,
(S)
OsO,, NAHSO,
a)
(S)oH
(R
H.
Reaction type
Cis Hydroxylation
Stereochemical
Enantiomers
Relationship
Mechanism:
EXAMPLE MECHANISM (you do not need to know this mechanism for Chem 345)
Rapent tove ut oppastasde
OH
HO.
OH
Transcribed Image Text:5) For the following reactions: a. Complete the reactions with both possible chiral products. b. Determine and label the absolute configuration (R or S) of all stereocenters. c. Label the reaction type and the stereochemical relationship (meso, enantiomer, diastereomer, or none). d. Draw out the reaction mechanism showing lone pairs, arrows, bond making/breaking, etc. for each reaction. CH (R) CH, (S) OsO,, NAHSO, a) (S)oH (R H. Reaction type Cis Hydroxylation Stereochemical Enantiomers Relationship Mechanism: EXAMPLE MECHANISM (you do not need to know this mechanism for Chem 345) Rapent tove ut oppastasde OH HO. OH
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