H-Ņ-C=C-HH.a. The bond between nitrogen and hydrogen is due to overlap of a(n)orbital.orbital and a(n)b. The lone pair on nitrogen is in what type of atomic orbital?c. The bond between N and C is due to overlap of a(n)orbital and a(n)orbital.d. The T-bonds between the two carbon atoms are due to the overlap oforbitals.

The orbital diagram for the following structure can be shown as:…

Answered: H-Ņ-C=C-H H. a. The bond between…

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter3: Electron Orbitals

Section: Chapter Questions

Problem 6CTQ

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Ethylene oxide is an intermediate in the manufacture or ethylene glycol (antifreeze) and polyester polymers. More than 4 million tons are produced annually in the United States. The molecule has a three-member ring of two C atoms and an O atom. (a) What are the bond angles in the ring? Comment on the relation between the bond angles expected based on hybridization an d the bond angles expected for a three-member ring. (b) Is the molecule polar? Based on the electrostatic poten1ial map shown below. where do the neg-alive and positive charges lie in the molecule? Polarity: It is a well separation of electric charge leading to a molecule or chemical compounds having an electrical dipole moment. Generally the polar molecules must contain polar bonds due to a different in electronegative between the bonded atoms. The electrostatic potential map clearly to explain, the oxygen atom has more negative () charge and other side has less positive () charge, so this molecule is a more polar nature.
- What orbital(s) are the lone pairs of electrons on the O atom placed? - What orbital is the lone pair of electrons on the N atom placed? - What type of bond(s) are formed between Ca1 – C? - What type of bond(s) are formed between C = O? - What type of bond(s) are formed between C – N? - What type of bond(s) are formed between N – Ca2? - What type of bond(s) are formed between N – H? - What is the angle between Ca1 – C = O? - What is the angle between Ca1 – C – N? - What is the angle between O = C – N? - What is the angle between C – N – Ca2?
Atom A has 4 valence electrons. Atom Z has 6 valence electrons. For the AZ3-2 ion How many valence electrons are in the structure? b. How many single bonds are in the structure? c. How many double bonds are in the structure? d. How many triple bonds are in the structure? e. How many lone pairs are on the central atom in the structure? f. What is the shape of the structure? g. What are the bond angles of this ion?
Part 1 What do each of the following sets of compounds/ions have in common with each other? a) SO3, NO3-, CO32- b) O3,SO2, NO2- Part 2 What do each of the following sets of compounds/ions have in common with each other? a) XeCl4, XeCl2 b) ICl5, TeF4, ICl3, PCl3, SCl2, SeO2
32W.) A pi bond is formed by the parallel overlap of s orbitalsX.) Since bromine is from Group VIIA, it needs 7 electrons to complete its octetY.) The bond angle between methane's bond pairs is 109.5⁰Z.) The orbital of f with a shape of y(3x²-y²) contains 14 electronsA.) If all 4 statements are trueB.) If 3 of the 4 statements are trueC.) If 2 of the 4 statements are trueD.) If only 1 of the 4 statements is trueE.) If none of the 4 statements is true
Draw an orbital picture of propene. The bond between and is formed by the overlap of which types of orbitals? a. sp2 and sp2 b. sp3 and sp3 c. sp2 on Ca and sp3 on Cb d. sp3 on Ca and sp2 on Cb The double bond between and is formed by what? a. two sigma bonds b. two pi bonds c. overlap of a p orbital on Cb with a sp2 orbital on Cc. d. overlap of two p orbitals plus overlap of two sp2 orbitals
On the left side of Figure 3.6, label the areas shown with a dotted line where... one bond can form. one bond can form.
Consider the following flat drawing of methane (CH4) . a. What is HCH bond angle implied by this drawing if you assume it is flat? b. Are the electron domains of this flat CH4 spread out as much as possible? c. Use model materials to make a model of CH4 (methane). If you assembled it correctly, thefour bonds (bonding electron domains) of your model will be 109.5° apart. d. In which representation, the drawing above or the model in your hand (circle one) are theH’s of CH4 more spread out around the central carbon? e. Confirm that your model looks like the following drawing. The wedgebond represents a bond coming out of the page, and the dash bondrepresents a bond going into the page f. You will often see methane drawn as if it were flat (like on the previous page). Why is thismisleading, and what is left to the viewer’s imagination when looking at such a drawing?
How many valence electrons does a neutral a. K atom have? b. C atom? N atom? O atom?
Explain how the dipole moment could be used to distinguish between the cis and trans isomers of 1,2-dibromoethene:
Which is the most polar bond? (a) CC (b) CH (c) NH (d) OH (e) Se-H
In Chapter 6, we study a group of organic cations called carbocations. Following is the structure of one such carbocation, the tert-butyl cation. (a) How many electrons are in the valence shell of the carbon bearing the positive charge? (b) Using VSEPR, predict the bond angles about this carbon. (c) Given the bond angle you predicted in (b), what hybridization do you predict for this carbon?

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