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Rank the following compounds in order of increasing (lowest to highest) boiling point
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- The chiral catalyst (R)-BINAP-Ru is used to hydrogenate alkenes to give alkanes . The products are produced with high enantiomeric excess. An example is the formation of (S)-naproxen, a pain reliever. Q.How can one enantiomer of naproxen be formed in such high yield?Trehalose, C12H22O11, is a nonreducing sugar that is only 45% as sweet as sugar. When hydrolyzed by aqueous acid or the enzyme maltase, it formsonly d-glucose. When it is treated with excess methyl iodide in the presence of Ag2O and then hydrolyzed with water under acidic conditions, only2,3,4,6-tetra-O-methyl-d-glucose is formed. Draw the structure of trehalose.Rank the following groups in order of decreasing priority. −CH=CH2, −CH3, −C≡CH, −H
- Suppose we aempt the conversion of fumaric acid to deuterated malic acid with BD3·THF,followed by oxidation with D2O2in NaOD(aq). Show all the possible stereoisomers (as Fisherprojections) that may be formed, and draw the mechanistic pathways (showing stereochemistry)that lead to these possible productsBy considering the stereochemical requirements for E2-elimination, and using an appropriate illustration need help indicating whether the more stable conformer (conformer B) of trans-1 can undergo E2 elimination. Thank you :)Given the solution to Example 8.5, predict the structure of the product(s) formed when 3-hexene is treated with NBS.
