Considering the following equilibria in an aqueous solution: (1) Ag+ +Cl- <---> AgCl(aq) K=2.0 * 10^3 (2) AgCl(aq) + Cl- <---> AgCl2 - K=93 (3) AgCl(s) <---> Ag+ + Cl- K=1.8*10^-10 (a) Find K for the reaction AgCl(s) <---> AgCl(aq). The species AgCl(aq) is an ion pair consisting of Ag+ and Cl- associated with each other in solution  (b) Find (AgCl(aq)) in equilibrium with excess AgCl(s).  (c) Find K  for AgCl2 - <---> AgCl(s) +Cl-.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter16: Solubility And Precipitation Equilibria
Section: Chapter Questions
Problem 37P
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Considering the following equilibria in an aqueous solution:

(1) Ag+ +Cl- <---> AgCl(aq) K=2.0 * 10^3

(2) AgCl(aq) + Cl- <---> AgCl2 - K=93

(3) AgCl(s) <---> Ag+ + Cl- K=1.8*10^-10

(a) Find K for the reaction AgCl(s) <---> AgCl(aq). The species AgCl(aq) is an ion pair consisting of Ag+ and Cl- associated with each other in solution 

(b) Find (AgCl(aq)) in equilibrium with excess AgCl(s). 

(c) Find K  for AgCl2 - <---> AgCl(s) +Cl-. 

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