Hydrogen chloride and oxygen react to form water and chlorine, like this: 4HCI(g)+O,(g) → 2H,0(g)+2Cl,(g) Suppose a mixture of HCI, O,, H,O and Cl, has come to equilibrium in a closed reaction vessel. Predict what change, any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whethe the equilibrium shifts to the right or left. perturbation change in composition shift in equilibrium to the right The pressure of HCl will ? to the left Some O, is removed. The pressure of H20 will ? (none) O to the right The pressure of HCl will ? Some Cl, is added. to the left The pressure of O2 will ? O (none)

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter14: Chemical Equilibrium
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Hydrogen chloride and oxygen react to form water and chlorine, like this:
4HC1(g)+O,(g) → 2H,0(g)+2Cl,(g)
Suppose a mixture of HCI, O,, H,O and Cl, has come to equilibrium in a closed reaction vessel. Predict what change, if
any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether
the equilibrium shifts to the right or left.
perturbation
change in composition
shift in equilibrium
to the right
The pressure of HCl will
to the left
Some 0, is removed.
The pressure of H20 will
(none)
to the right
The pressure of HCl will
to the left
Some Cl, is added.
The pressure of O, will
(none)
Transcribed Image Text:Hydrogen chloride and oxygen react to form water and chlorine, like this: 4HC1(g)+O,(g) → 2H,0(g)+2Cl,(g) Suppose a mixture of HCI, O,, H,O and Cl, has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation change in composition shift in equilibrium to the right The pressure of HCl will to the left Some 0, is removed. The pressure of H20 will (none) to the right The pressure of HCl will to the left Some Cl, is added. The pressure of O, will (none)
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