(i) Compare the calculated Eo to that of the actual [measured] lemon battery above, what is the % difference? (ii) why are they different? (c) calculate the Gibbs Free Enegy, DGo,of actual the lemon cell above

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter17: Electrochemistry
Section: Chapter Questions
Problem 76AP
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Can you please solve 1C (i), (ii), c, d, e and f? Thanks. I included the answers for the cathode, anode, and Ecell. You can use that to solve the rest of the questions thanks. and also the Eo of actual lemon battery used is 0.906volts

Nernst Equation:  E = E° – (RT/nF) ln Q

DGo = -nFEo = -RTlnK

  1. Using Cell Notation and in not more than 2 lines, describe how to make a battery at home from plant source.

  My Electrolyte =  _lemon juice_________________

 

1b. Write balanced half-cell and overall equations for the reaction taking place in the described battery in 1.

answer= Cu^2+(aq) +2e^- =Cu(s)......(1), E^o=0.34v

               Zn(s)=Zn^2+(aq) + 2e^-.......(2), E^o=-0.76v                          

1c. For the cell above,

  • Calculate the standard electrode potential, Eo, for the balanced redox equation.

answer for 1c= Ecell=Ecathode - Eanode=0.34-(-)0.76v=1.10v.

(i) Compare the calculated Eo to that of the actual [measured] lemon battery above, what is the % difference?

(ii) why are they different?

(c) calculate the Gibbs Free Enegy, DGo,of actual the lemon cell above

(d) Is the cell reaction spontaneous?

(d) Why?

(e) Calculate the Keq for the cell

(f) What is the ratio of the concentration of the [oxidized ion] to that of the [reduced ion] at equilibrium

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