(i) Explain how the mass of the particle(s) involved affects the separation between energy levels in quantum mechanics. (ii) Explain why the sensitivity of an NMR experiment is affected by the strength of the applied magnetic field. (iii) Explain why, to a good approximation, rotational and vibrational transitions do not change the energies of electrons.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter15: Introduction To Electronic Spectroscopy And Structure
Section: Chapter Questions
Problem 15.58E
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(i) Explain how the mass of the particle(s) involved affects the separation
between energy levels in quantum mechanics.
(ii) Explain why the sensitivity of an NMR experiment is affected by the strength of
the applied magnetic field.
(iii) Explain why, to a good approximation, rotational and vibrational transitions do
not change the energies of electrons.
Transcribed Image Text:(i) Explain how the mass of the particle(s) involved affects the separation between energy levels in quantum mechanics. (ii) Explain why the sensitivity of an NMR experiment is affected by the strength of the applied magnetic field. (iii) Explain why, to a good approximation, rotational and vibrational transitions do not change the energies of electrons.
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