(i) (ii) (iii) (iv) dissociation constant of [Cu(NH 3)4]2+ is x × 10-12, then value of 'x' is Cu2+ + NH3 = [Cu(NH3)]²+ [Cu(NH3)]2+ + NH3 [Cu(NH3)2]2+ + NH3 [Cu(NH3)3]2+I+ NH3 k1 = 104 %3D [Cu(NH3)2]?+ [Cu(NH3)3]2* [Cu(NH3)4] 2* k2 = 2 x 103 k3 = 5 x 102 k4 = 100

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter19: Complex Ions
Section: Chapter Questions
Problem 43QAP: Ti(NH3)63+ has a d-orbital electron transition at 399 nm. Find o at this wavelength.
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e [Cu(NH3)J²*
(i)
(ii)
(ii)
Cu2+ + NH3
k1 = 104
k2 = 2 x 103
2+
[Cu(NH3)]2+ + NH3
[Cu(NH3)2]2+ + NH3
[Cu(NH3)3]2+I+ NH3
[Cu(NH3)2]2*
[Cu(NH3)3]2*
[Cu(NH3)4] 2*
k3 = 5 x 102
(iv)
dissociation constant of [Cu(NH 3)4]2+ is x × 10-12, then value of 'x' is
k4 = 100
Transcribed Image Text:e [Cu(NH3)J²* (i) (ii) (ii) Cu2+ + NH3 k1 = 104 k2 = 2 x 103 2+ [Cu(NH3)]2+ + NH3 [Cu(NH3)2]2+ + NH3 [Cu(NH3)3]2+I+ NH3 [Cu(NH3)2]2* [Cu(NH3)3]2* [Cu(NH3)4] 2* k3 = 5 x 102 (iv) dissociation constant of [Cu(NH 3)4]2+ is x × 10-12, then value of 'x' is k4 = 100
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