Interpret the analytical date reported including reference to IR NMR chemical shifts integration and observed splitting patterns

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Interpret the analytical date reported including reference to IR NMR chemical shifts integration and observed splitting patterns

 

H.
N'
CI
NH2
Strucutre 2
Strucutre 1
Strucutre 3
H.
F.
N.
CI
NH,
Strucutre 4
Strucutre 5
Strucutre 6
CI
N.
H.
N.
CI
NH,
Cl
Strucutre 7
Strucutre 8
Strucutre 9
O:
ZI
Transcribed Image Text:H. N' CI NH2 Strucutre 2 Strucutre 1 Strucutre 3 H. F. N. CI NH, Strucutre 4 Strucutre 5 Strucutre 6 CI N. H. N. CI NH, Cl Strucutre 7 Strucutre 8 Strucutre 9 O: ZI
You are asked to identify an unknown compound, which has the following analytical
data:
8.
6.
4
PPM
3.
Chemical Shift
8.28
Integration
Multiplicity
1
7.95
7.48
1
d.
1
S
6.99
4.11
1
2
2.81
3
S
1.34
3
The peak at 8.28 ppm is found to disappear when the NMR sample is treated with
D20
The IR spectrum of the unknown has the following key peaks;
a sharp strong peak at 1680 cm-1
a broad signal at 3250 cm1
The compound has a molecular weight of 213.66
You have been provided with 9 possible structures of the unknown compound.
Transcribed Image Text:You are asked to identify an unknown compound, which has the following analytical data: 8. 6. 4 PPM 3. Chemical Shift 8.28 Integration Multiplicity 1 7.95 7.48 1 d. 1 S 6.99 4.11 1 2 2.81 3 S 1.34 3 The peak at 8.28 ppm is found to disappear when the NMR sample is treated with D20 The IR spectrum of the unknown has the following key peaks; a sharp strong peak at 1680 cm-1 a broad signal at 3250 cm1 The compound has a molecular weight of 213.66 You have been provided with 9 possible structures of the unknown compound.
Expert Solution
steps

Step by step

Solved in 3 steps with 3 images

Blurred answer
Knowledge Booster
Electron Paramagnetic Resonance
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY