IR Spectrum (quid film) 4000 100 8282& 80 60 40 20 % of base peak 3000 43 40 13C NMR Spectrum (500 MHz, CDCI, solution) 80 DEPT CH CH CH proton decoupled 200 ¹H NMR Spectrum 2000 V (cm'¹) M** 122/124 120 160 m/e 1600 160 1200 120 800 Mass Spectrum C3H,Br 280 solvent 80 200 240 Problem 15 No significant UV absorption above 220 nm 40 08 (ppm)

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section: Chapter Questions
Problem 20.26P
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Question
121
Problem 15
IR Spectrum
(lquid fam)
4000
3000
2000
1600
1200
800
v (cm')
100-
43
Mass Spectrum
80
60
40
No significant UV
M*
122/124
absorption above 220 nm
20
C3H,Br
trum
wou
40
80
120
160
200
240
280
m/e
13C NMR Spectrum
(50 0 MHz. CDCI, solution)
pled
scouple
DEPT CH CHt CHt
20
solvent
proton decoupled
Spect
200
160
120
80
40
8 (ppm)
H NMR Spectrum
(200 MHz, CDCI, solution)
expansions
4.6
40
ppm
20
14 ppm
TMS
业
10 9
8 7
6 5 4
3
2
8 (ppm)
104
Sof base peak
Transcribed Image Text:121 Problem 15 IR Spectrum (lquid fam) 4000 3000 2000 1600 1200 800 v (cm') 100- 43 Mass Spectrum 80 60 40 No significant UV M* 122/124 absorption above 220 nm 20 C3H,Br trum wou 40 80 120 160 200 240 280 m/e 13C NMR Spectrum (50 0 MHz. CDCI, solution) pled scouple DEPT CH CHt CHt 20 solvent proton decoupled Spect 200 160 120 80 40 8 (ppm) H NMR Spectrum (200 MHz, CDCI, solution) expansions 4.6 40 ppm 20 14 ppm TMS 业 10 9 8 7 6 5 4 3 2 8 (ppm) 104 Sof base peak
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