Is the reaction [Co(CN)5]3- + Co(NH3)5(OH)]2+likely to proceed by an inner-sphere or out-sphere mechanism? Explain your answer.

Q: Chromium forms two common anionic carbonyl compounds: [Cr(CO)5]n- and [Cr(CO)4]m-. Deduce the…

A: The coordination compounds follows the EAN rule. To find the charge, first of all find the number of…

Q: x-1-2 = 0- x = +3 NH3 LANH3 NH3 ONO ove Name of complex #3: Pentamminenitro-O-Cobalt (III) Chloride…

A: We have to find the oxidation state of central metal atom then see the linkage isomers and according…

Q: Predict the major produc 1) H2, Lindlar's catalyst 2) HBr Br Br Br Br Br В E D C A

A: Lindlar catalyst: Alkynes can be selectively reduced to an alkene by a Lindlar catalyst. The Lindlar…

Q: Which reaction is the example of dissociation reaction? O a. Adding LiMe into [Ir(PME3)4]CI to form…

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Q: Some reactions in organometallic chemistry involve the insertion of small molecules into…

A: In the given complex, Tc (Technitium) has a coordination number of 5 and is coordinated to four…

Q: Draw a structure for cis-dichlorobis(ethylenediamine)cobalt(III) ion. Is this ion chiral? Is the…

A: The species will be the chiral compound if they will not be superimposed in the mirror while if they…

Q: Could Cr(s) react with Pb(NO3)2

A: Could Cr(s) react with Pb(NO3)2 ?

Q: Explain the observation that the pentacyanocobaltate(II) ion catalyzes the conversion of…

A: Given: CoCN5NCS3- ⇔CoCN5SCN3- In both complexes, the oxidation state of Co (Cobalt) is +3.

Q: Which series correctly place the ligands in order of increasing nephelauxetic effect a) F-<Cl-<I-…

A: Order of the ligands based on nephelauxetic effect.

Q: Which of the following classes of ligands has the strongest trans effect? а. A o-acceptor ligand b.…

A: The legand which contains π - bond and ,are π-acceptor have greatest trans effect.

Q: outer-sphere mechanism: [Cr(OH2)6]2+ + [IrCl6]2- ⇄ [Cr(OH2)6]3+ + [IrCl6]3- inner-sphere mechanism:…

A: The inner and outer complexes is explained below:

Q: 3. The rate constants for the formation of trans-[PtCIY(PET3)2] from trans-[PtCl2(PEt3)2] for Y :…

A: Ligand substitution reaction in square planar complexes. Complexes with d8 configurations usually…

Q: a) Name each of the following complexes according to IUPAC rule i) [Ni(NO)2(ONO)(Br)] ii)…

A: The IUPAC names of the above-given coordination complexes are as follows:…

Q: Which of these types of elementary inorganic reactions changes the oxidation state of the transition…

A: Concept introduction- Oxidation state- The number of electrons lost or gain by an atom when atom is…

Q: Which of the following reactions has two transition states in its energy dingram? OA SNI O B. SN2…

A: This can be explained as follows.

Q: Which of the following complexes may undergo b-H elimination O Al [(CH,Si(CH3)al2 (Et) O…

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Q: A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction:…

A: Monodentate ligands bind to other molecule through only one donor atom and bidentate ligands bind to…

Q: What will happen to the C=C bond of the ligand and oxidation state of the metal centre upon…

A: This reaction is the oxidation reaction in organometallic compound.

Q: The reaction: Mn(CO)5(CH3) + CO → Mn(CO)5(COCH3) is an example of:   a. ligand addition   b.…

A: The given reaction of the Mn complex is: Mn(CO)5(CH3) + CO → Mn(CO)5(COCH3)

Q: In an inner-sphere electron transfer reaction, which of the following ligands would be the "worst"…

A: Since you have posted multiple questions, we will solve only first question for you. If you want the…

Q: Draw the molecular structures of the following complexes: (1) Tungstenocene dihydride (ii)…

A: Since you have posted a question with multiple sub-parts, we will solve first three subparts for…

Q: Which of the following compounds follow the effective atomic number rule, and which do not?(27Co,…

A: Effective atomic number rule is defined as the total number of electrons present around the central…

Q: The cis isomer of tetraamminedichlorocobalt(III) bromide appears red while the trans isomer appears…

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Q: 4. What are the products (show stereochemistry where relevant)? a. b. co,CH, ćo, CH, d. OCH,

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Q: What will happen to the C=C bond of the ligand and oxidation state of the metal centre upon…

A: In organometallic chemistry, a metallacycle is a derivative of a carbocyclic compound wherein a…

Q: #2

A: The general formula for the calculation of electron count in a given formula is shown below.…

Q: Hexaamminecobalt(11) chloride is the complex .a (Co(NH3)6)3+ .b [Co(NH3)4|Cl4 [Co(NH3)6]Cl3 .d…

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Q: Answer the questions below regarding the orbital diagram for the metal ion in Rh(OH2)6²* (high spin)…

A: “Hello. Since you have posted a question with multiple sub-parts, we will solve the first three…

Q: When Cr(NH3)2(CO)4 undergoes ligand substitution, will the intermediate be associate or dissociative…

A: A question based on ligand substitution in coordination complex, which is to be accomplished.

Q: A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction:…

A: Dissociation reaction is the combination of Dissociation followed by association of ligand.  Thus…

Q: 1-For the reaction,  4 Cl- + Co(H2O)62+   CoCl42- + 6 H2O                     (color 1)…

A: 1. Given:

Q: Transition metal chemistry: 4. Provide the products/reagents for each reaction. LOCH₂ + b. d. f.…

A: According to our guidelines only three sub-parts can be answered. Kindly repost the question again…

Q: The insertion reaction of CO2 in [Rh(Me)(PMe3)4] is shown as below: Me MezPl..Rh-PMe3+ CO2 A…

A: The carbon dioxide group get inserted between the methyl group and metal, the oxidation state of the…

Q: The d-d transition in CrCl4 2- is at lower energy than Cr(NH3)62+. Briefly explain.

A: A question based on d-d transition, which is to be accomplished.

Q: A) Which of the following complexes would have a lower activation energy under a dissociation…

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Q: Which complex below is the MOST stable? a. [FeCl2(NH3)2] O b. [Ticl2(NH3)2] O c. [MnCl2(NH3)2] O d.…

A: Crystal field stabilization energy is defined as difference in energy between t2g and eg set of…

Q: Predict the site of nucleophilic attack in each of the complexes shown in (i)-(iv) below and draw…

A: “Since you have posted a question with multiple sub-parts, we will solve the first three subparts…

Q: Suggest a plausible route by which a carbonyl ligand in [Mo(Cp)(CO)3(CH3)] might exchange for a…

A:

Q: 3. The insertion reaction of CO2 in [Rh(Me)(PMe;)4] is shown as below: Ме MegPl. Rh- -PME3+ CO2 A…

A: ii Oxidation state Rh in complex A as well as      Rh MePMe34 or  RhMePMe34 is +1

Q: What is a possible product of the following reaction? OCH₂ AB Br A + Cl₂ OCH₂ OCH ₂ CI a d d Br CI…

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Q: reaction of [Co(NH3)4Cl2]+ with H2O is 103 times faster than the reaction of [Co(NH3)5Cl]2+. By…

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Q: Which of these complexes would have the greatest ∆O value? [CoF6]3- [CoCl6]3- [CoBr6]3-

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Q: Method 1 (racemic) Method 2 (racemic)

A: A question based on epoxidation of alkenes, which is to be accomplished.

Q: The product formed when Cr(H2O)6+3 is hydrolyzed:     a Cr(OH)2(H2O)6+3   b Cr(OH)2(H2O)5+2…

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Q: Using the concept of trans activating ligands, predict the following reaction products (A, B, C, D,…

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Q: Is the reaction [Co(NH 3 ) 6 ]^ 3+ +[Cr(H 2 O) 6 ]^ 2+ likely to proceed by an inner-sphere or outer…

A: In outer sphere electron transfer, complexes does not undergo substitution and no new bonds are…

Q: 1. The Cp2Rh2[p-(CF3C=CCF3)](CO)(CNR) complex has a Rh-Rh bond distance of 2.67 Å, strongly…

A: In the given question we have to calculate the electron count of the given compound and to show it…

Q: Which of the following compound/s are correct in the given statements? 1.What compound/s will be…

A: We have to find the compound.

Q: 20. Carbenes bind to metal centres synergistically, but which of these statements is/are true? 1.…

A: 20. Carbenes are highly reactive species which contains divalent carbon atoms that is, carbon atoms…

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.