Label all major absorbance bands in the following  IR spectrum specifying the absorptions associated with the C=O, C-O, and C-H bonds

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Label all major absorbance bands in the following  IR spectrum specifying the
absorptions associated with the C=O, C-O, and C-H bonds  

95
90
85
80
75
70
55 -
50
45
40
35
2500
1000
Wavenumbers (cm-1)
% Transmittance
2972.12
2878.09
1705.80
1653.24
1506.79
1476.55
1364.97
1355.35
1274.55
1135.29
953.44
832.79
671.74
Transcribed Image Text:95 90 85 80 75 70 55 - 50 45 40 35 2500 1000 Wavenumbers (cm-1) % Transmittance 2972.12 2878.09 1705.80 1653.24 1506.79 1476.55 1364.97 1355.35 1274.55 1135.29 953.44 832.79 671.74
Experiment: Pinacol-Pinacolone (PP)
Title:
Pinacol Rearrangement. 2,3-Dimethyl-2,3-butanediol to 3,3-Dimethyl-2-butanone
Ref:
Hill, G. A.; Flosdorf, E. W. Organic Syntheses Collective Volume 1 (1941; 2nd Ed) p 462.
Purpose: Synthesize 3,3-dimethyl-2-butanone, A Pinacol-Pinacolone Rearrangement Example.
6Nsulfuric acid
steam distill
Reagent table:
Reagent
(source)
Mwt
mp °C
bp °C
mmol
equiv
density
volume
mass
pinacol
(Aldrich)
(98% anhydrous)
118.18 40-43
171-2
50.8
1.00
6.10 g
(739 torr)
5.08 g
3,3-dimethyl-
2-butanone
100.16
-50
106.2
50.8
1.00
0.80 g/mL 6.4 mL
90
1.76
30 mL
H2SO4 (6 N, 28%)
(Fisher)
Procedure:
Add oo 1 ml ofweter te the
tory funnel (bereeshee olemped on c
all ringotond) ond
Transcribed Image Text:Experiment: Pinacol-Pinacolone (PP) Title: Pinacol Rearrangement. 2,3-Dimethyl-2,3-butanediol to 3,3-Dimethyl-2-butanone Ref: Hill, G. A.; Flosdorf, E. W. Organic Syntheses Collective Volume 1 (1941; 2nd Ed) p 462. Purpose: Synthesize 3,3-dimethyl-2-butanone, A Pinacol-Pinacolone Rearrangement Example. 6Nsulfuric acid steam distill Reagent table: Reagent (source) Mwt mp °C bp °C mmol equiv density volume mass pinacol (Aldrich) (98% anhydrous) 118.18 40-43 171-2 50.8 1.00 6.10 g (739 torr) 5.08 g 3,3-dimethyl- 2-butanone 100.16 -50 106.2 50.8 1.00 0.80 g/mL 6.4 mL 90 1.76 30 mL H2SO4 (6 N, 28%) (Fisher) Procedure: Add oo 1 ml ofweter te the tory funnel (bereeshee olemped on c all ringotond) ond
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