Mention the optimum conditions required for good performance of: i. Chelating agent in metal separation ii. Rule of primary ions in separation by ion exchanger ii. Distribution ratio in liquid-liquid and liquid solid separations. v. Ion exchange (Type and mechanism)
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Q: Nickel bis-dimethylglyoximate complex was depősited with a weight of (4.869g) with the filter paper…
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- Nickel bis-dimethylglyoximate complex was deposited with a weight of (2.721g) with the filter paper from the base medium from adding (10ml) of hot DMG to a salt of nickel chloride at weight (0.4g), find the percentage of nickel ion. Note that the weight of the filter paper (0.78g).Nickel bis-dimethylglyoximate complex was deposited with a weight of (4.869g) with the filter paper from the base medium from adding (10ml) of hot DMG to a salt of nickel chloride at weight (0.78g), find the percentage of nickel ion. Note that the weight of the filter paper (1.30g). At.Wt.: Ni= 58.69 g/mol, C= 12 g/mol, O=16 g/mol, H=1 g/mol, N=14 g/molA 50.00mL sample with BaCl2 was diluted to 650 mL. Aliquots of 100.00 mL of this solution were analysed using Mohr and Volhard methods. The following data were obtained. Volhard method: Volume of AgNO3 = 100mL; Volume of KSCN = 18.25mL Mohr Method: volume of AgNO3: sample = 27.80mL (blank) = 0.30mLWhat is the %BaCl2 using Mohr and Volhard Method. Concentration of KSCN: 0.04000M Concentration of AgNO3: 0.03000M
- Predict the multiplicity/splitting pattern and indicate the integration value for each Hydrgen present in the boxes. Provide the simplest ratio.Explain why Anodic Stripping Voltammetry (ASV) is considered superior over analytical techniques in terms of detection limit.Graphite furnace atomizers are renowned in Atomic Absorption Spectrometry for their exceptionally low detection limits (10-12 g and lower for many elements). Why are detectabilities so much better with graphite furnaces than with flame atom cells in AAS?
- A dual beam UV-visible spectroscopy was used to determine the levels of Fe(II) in the run-off water of a local mine using the ferrozine assay (i) During a check of the instrument a step-like feature at 360 nm was observed in spectrum of the standard. Suggest what may give rise to this with reference to the instrument configuration and comment on how it may be remedied. (ii) The molar absorptivity of the [Fe(Ferrozine)3]2+ complex is 27900 cm−1 M−1 at 562 nm in aqueous solution (pH 5.5). If the EU maximum contaminant level for Fe is 200 ug /L and the contract required detection limit is 100 ug/L, comment on the suitability of the assay for the detection of iron. (iii) Determine the sample range, in terms of concentration and ppm, of Fe(II) that can be confidently analysed by UV-visible spectroscopy using a 1 cm cuvette. Explain with reference to an appropriate equation and solution phenomena, the origin of the limitations that define this rangePlease help me fill the remaining spaces. The spaces marked with NA don't need to be calculate. Name Molecular Weight Amounts used mmol Equivalents M.P or BP (C) Density (g/mL) Indene 116.16 .5mL MP=-2 BP=181-182 .996 Borane-tetrahydrofuran Complex 85.94 2.8mL 1 MP= -108 BP=66 NA 30% Hydrogen Peroxide 34.01 1mL MP= -33 BP=108 NA 3 M NaOH(aq) 40 .7mL MP=318 BP=1390 NA Diethyl Ether 74.12 NA NA NA BP=75-78 .902 Hexanes 86.17 NA NA NA BP=65.5-68.3 .659 Potassium Permanganate 158.03 NA NA NA BP=100 1.0 1-Indanol (Product) 134.13 NA MP=50-54 NA 2-Indanol (Product) Same as Above Same as Above Same as Above NA MP=68-71 NAThe accompanying data (1.00-cm cells) were obtained for the spectrophotometric titration 10.00 mL of Pd(II) with 2.44 10-4 M Nitroso R(O. W Rollins and M. M. Oldham, Anal. chem .,1971, 43, 262, DOI: 10.1021/ac60297a026). Calculate the concentration of the Pd(II) solution, given that the ligand-to-cation ratio in the colored product is 2:1
- 21. (What exactly is meant by potentiometric methods? What are they even?)(i) You have been provided with a sample collected from a water pool beside a slag heap at the iron ore mine. 35 uL of the sample is added to 1165 uL of buffered ferrozine (excess). If the %T recorded at 562 nm in a 2 mm cuvette is found to be 25%, calculate the concentration of Fe(II) in the sample in mol L−1 and ppm. Comment on the contamination level. (ii) Comment on a possible contaminant that could interfere with the assay and suggest an approach that could be used to account for its presence.A solution of altura red of concentration 307 ppm gives an absorbance of 0.616. What concentration is a solution of allura red which gives an absorbance reading of 0.261? The same cell (cuvette) with a path length of 1.000 cm is used for both readings. Report your answer to the nearest whole number without units? Hint: A=abc, where c can have any concentration units. dont provide handwriten solution