Nitrogen monoxide and ozone react to form nitrogen dioxide and oxygen, like this: NO(g)+O3(g) → NO2(9)+O2(g) The reaction is exothermic. Suppose a mixture of NO, O3, NO, and O, has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation change in composition shift in equilibrium to the right to the left The temperature is raised. The pressure of 02 will go up. O (none) go down. not change. to the right The temperature is lowered. to the left The pressure of NO will (none)

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Chapter17: Spontaneity, Entropy, And Free Energy
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Problem 8RQ: Consider the equation G = G + RT ln(Q). What is the value of G for a reaction at equilibrium? What...
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Nitrogen monoxide and ozone react to form nitrogen dioxide and oxygen, like this:
NO(g)+O3(g) → NO,(9)+O2(g)
The reaction is exothermic. Suppose a mixture of NO, O3, NO, and O, has come to equilibrium in a closed reaction vessel. Predict what change, if any, the
perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left.
perturbation
change in composition
shift in equilibrium
to the right
to the left
The temperature is raised. The pressure of O2 will
v ?
O (none)
go up.
go down.
not change.
to the right
The temperature is
lowered.
to the left
The pressure of NO will
?
O (none)
O O O
Transcribed Image Text:Nitrogen monoxide and ozone react to form nitrogen dioxide and oxygen, like this: NO(g)+O3(g) → NO,(9)+O2(g) The reaction is exothermic. Suppose a mixture of NO, O3, NO, and O, has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the table below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation change in composition shift in equilibrium to the right to the left The temperature is raised. The pressure of O2 will v ? O (none) go up. go down. not change. to the right The temperature is lowered. to the left The pressure of NO will ? O (none) O O O
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