Nitrous Acid Test Procedure: Make a solution of 4 grams NaNO3 in 16 mL water. Put 2 mL of concentrated hydrochloric acid into a 10x75-mm test tube and add 0.5 ml of amine. Cool the solution in a water-ice slush to zero degrees celcius. Add the nitrile solution slowly, dropwise, until a drop of the reaction mixture gives a blue spot on starch-iodide paper. The following should be tested: (NOTE: Include the observations and reaction equation) A. PRIMARY ALIPHATIC AMINES (Like Butylamine of Cyclohexylamine) B. PRIMARY AROMATIC AMINES I. Aniline + nitrous acid; then heat. II. Aniline + nitrous acid; then B-Napthol.

Nitrous Acid Test Procedure: Make a solution of 4 grams NaNO3 in 16 mL water. Put 2 mL of concentrated hydrochloric acid into a 10x75-mm test tube and add 0.5 ml of amine. Cool the solution in a water-ice slush to zero degrees celcius. Add the nitrile solution slowly, dropwise, until a drop of the reaction mixture gives a blue spot on starch-iodide paper. The following should be tested: (NOTE: Include the observations and reaction equation) A. PRIMARY ALIPHATIC AMINES (Like Butylamine of Cyclohexylamine) B. PRIMARY AROMATIC AMINES I. Aniline + nitrous acid; then heat. II. Aniline + nitrous acid; then B-Napthol.

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter13: The Chemistry Of Solutes And Solutions

Section: Chapter Questions

Problem 83QRT

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