OH 10) Т. NANE THE FF. ) CH, CH CH, CH CH3 CH3 OH 2) CH, CEC CH CH, CH, OH CH, CH= CH CH, CH CH OH 3) 4) CH, = CH CH, CHO 2. CHO 5) CH3 6) el Br 7) CH, CH CH CH CHO OH CI Br 8) CH, C с с сн, снО 9) CH, G CHO

Q: What are the products of the following reactions? Indicate whether each reaction is an oxidation or…

A: The given reaction is an oxidation reaction since two oxygen atoms gets added over the carbon-carbon…

Q: H2SO4 14.8 CH3CH2CH,OH 140°C a) CH;CH=CH2 b) (CH3)½CHOCH(CH3)2 c) CH;CH,CH,OCH,CH,CH3 d)…

A: This as E1 reaction .This involves formation of carbocation intermediate . Which rearranges to…

Q: D CH=CH,. H* 2) KMuO,. A OH CH CH CHCH, сон a. b. CH,CH, CH,CO,H d.

A: Given reaction is :  The product of the reaction = ?

Q: (a) CH3COO¯ + HCN = CH;COOH + CN (b) HCO, + HCO; = H,CO3 + CO?- (c) H2PO, + NH3 (d) HCIO + CH;NH2 =…

A: According to Bronsted Lowry, In a chemical reaction,  an acid is a substance who can donate H+ ion…

Q: CH3 *NH3 CH3 НС-ОН HC-CH,-CH,OH CH, O=C CH2 CH2 C=0 CH3 NH CH, CH, HC-CH,-CH,OH CH CH, C=0 CH CH, NH…

A:

Q: H (CH3)½CO-K* H,CH,C (CH3),COH

A: Elimination reactions results in lost of atoms or group of atoms resulting in the formation of a…

Q: CH,CH,CH,NHCH, ? HO* CHO ? 6. 7. ? Zn, H,O* + 5.

A: Given,

Q: CH,CH3 CH3 CH3 CH,CH, 10. Br 1. 5. CH,CH,CH, CH3 CH,CH,CH, CH3 `CH3 2. CH,CH,CH, 6. Br 11. CH3 H,C…

A:

Q: CH3 HO, HO CH, Br *OH CH3 H,C Br Br

A: We follow the below steps to assign IUPAC nomenclature to an organic compound.  Step-1: Select the…

Q: 1.) HAI(Bu), or DIBAL-H 2.) H,0", H,0 CEN: H. R' H. 3 3 1.) HAI('Bu)2 or DIBAL-H 2.) H,O*, H,O…

A:

Q: a) CN H,O, H* CH3 OH b) H3C- CH3 c) CH3 KMNO4, A, H,0* CH3 d) Br Mg, éther CO, H*

A: The given organic transformations are examples of the formation of the amide, anhydride, oxidation…

Q: CH,CH,OH H;SO, CH , a. CH [1] BH3 b. (2] H2O2, OH Br2 C. エエ

A: Since you have posted a question with multiple sub-parts, we will solve first three sub-parts for…

Q: 3) CHy Ć c CH2 C Hq CH, OH CH3 11 4) CH, C CH CH, CH CH, COOH 5) CH, = CH CH, CH=CH CH, CHO %3D

A:

Q: Identify A through H.

A: When methyl bromide is treated with the Li-atom and Cul gives the corresponding organometallic…

Q: а) Na OCH,CH; CHCH-OH, 78° с Na SCH,CH; DMF, 0° C b) CH;OH CH3 22° C Br K°BC(CH;); (CH;);COH, 82° C

A: substitution and elimination reaction are the basic fundamental of organic reaction which always…

Q: (а) Cl НО (b) Н—он (с) H' Br CH, CH, н он CH,Br CH,Br CH, () Н— Br -H- (е) Н— Br ) Н- -Br H -Br Br H…

A: Since you have posted a question with multiple sub- parts, we will solve first three sub- parts for…

Q: Suggest a suitable series of reactions for carrying out each of the following synthetic…

A: Hello. Since your question has multiple sub-parts, we will solve first three sub-parts for you. If…

Q: 2. 3. H3C H + CH3OH (+ excess CH3OH, H+) → (h) CH3CH₂OH + PCC → (i) Br (i) + Mg (j)

A: In this question, we will draw the structure of the products (h), (I) and (j)  You can see the…

Q: H ÇH,OH H H H CI (а) Cl НО (b) Н- (е) H -ОН Br CH, CH, H OH ÇH,Br CH,Br CH, (е) Н— Br (() Н— Br (g)…

A: Since you have posted a question with multiple sub- parts, we will solve first three sub- parts for…

Q: a mechanism for each of the following reactions:

A:

Q: H,0 H,CrO, CH,NH. H+ NABH,CN он но -H- NABH но -OH HO, CH,OH H,C. HO, Br Br H,CO NaBH, H+ agua CH,OH…

A: H2CrO4 oxidizes secondary alcohol to ketone Ketone undergoes reductive amination with amine in the…

Q: CH, 1)0, 4) CH, 2) Z HOAC 1. Hg(OAchyTHF-H,0 2. NaBH OH HCN H,0 6) CH 1. BH, THE 2. H,O, OH H,SO,…

A: Hello. Since your question has multiple sub-parts, we will solve first three sub-parts for you. If…

Q: 4. H2O + HCl = H3O* + Cl 5. NH3 + HF = NH,* + F

A:

Q: (C,H,),CuLi CHS HOCH,CH,OH CH3 H,NNHC,H, CH3

A:

Q: Cl CH,-С - CH, -ОН CI Br | CH, - CH, - C - CH, - CH - CH, OH OH

A: The IUPAC name for the given molecule is to be written. In naming organic compounds, the functional…

Q: 1) Оз 2) Zn, Hз0* CH3 + OH H,C H3C-N CH, CH3 王 180 °C 1 NaNH. CH 2. CH,CH,CH,Br

A: 1). The first reaction is the ozonolysis of cycloalkene which takes place in the presence pf O3 and…

Q: (CH),CuLi CH3 b) HOCH,CH,OH CH3 c) H,NNHC,H, HC. CH3

A:

Q: он a) CH,CH,CHCH3 H2SO, isi NANH2 b) CH,CHCH,CI NH, c) CH,CH=CCH,CH3 HBr

A:

Q: CH,COH H;SO, CH, KCr,O, CH;COOH H;SO, K.Cr,O, CH CHOH

A: Balance Chemical equation means no of atoms should be equaal in both side reactant and product

Q: OH Cro3 HBr -OH H,SO4 а) CH, PPh, b) H;C -CH3 CH;OH H,SO,

A:

Q: Which reaction in each of the following pairs takes place more rapidly? (EtOH is ethyl alcohol; Et2O…

A: (a)In one reaction HO- is used as nucleophile whereas in another one water is used as nucleophile.…

Q: HNO, (1 eq.) H2SO, Br 0 °C NO2 HNO, (1 eq.) H2SO, 0 °C он

A:

Q: H H3C CH,CH3 H. CH,CH3 Но Br H3C Br HO, CO,H F CH,CH3 H- -HO- Но CO,H CH,CH3

A:

Q: CH, B CH, Br CH3 Br CH3 Br CH; Br CH3 Br CH3 Br CH3 Br CH; Br CH3 CH3 CH3 Br Br Br.

A: diastereoisomers are the compounds that are non-mirror images of each other or we can say that the…

Q: 1.03, CH2C12 2.Zn, НOАс b. 1. HgOAC)2, H,0 2.N ABH4 CH=CH2 Ch H2O

A: The reactions that involving organic compounds are known as organic reactions.  Alkenes are the…

Q: а. NaOH + HC1→ NaCl + H2O b. Pb2+ + 2C - PbCl2 с. AGNO; + HC1 → HNO3 + AgCi d. 2HC2H;O2 + Ca(OH)2 →…

A: Redox reaction

Q: 1. CH;CH,CH,CH,MgBr а) `CH3 2. H30* (CH;CH2),CuLi b) 1. 2 eq. CH3CH,MgBr c) 2. H2O 1. NABH4 d) 2.…

A: Given,    Major products of the reactions = ?

Q: (a) CH,CH,OH HyC=CH, + H20 (b) CH2=CHCH,CI + H20 CH=CHCH,OH + HCI MgBr CH, (с) CH,CH + -c-OMgBr (d)…

A:

Q: 10. OCH3 7. CH 11. 8. CH;CH,CH(NH,)CH3 CH3-0-CH,CH,CH,CH3 Hi, N(CH3)2 12. 9. CH;CH2CH2CHCH2CH,OH

A: According to IUPACN Nomenclature, naming of organic compounds involves the following part . word…

Q: Draw the products of each reaction.

A: Let us discuss in brief about the following reactions: In part, a and b esterification takes place…

Q: Can you help me solve this?

A: The given organic reactions are solved

Q: H H H H -С -О-С-С-Н НН Н НН Oa CH3 H3C НННН 111 н-с-с-с-с-OH - НННН SH CH3 CH3 Н Н нннно IIII 0…

A:

Q: CH, CH, Br CI CH;- El CI CH, CH, (3) ČI (1) (2) CH3 CH, CH,Br CH CH CH CH CH, CH, CH, (4) (5) (6)…

A: We have seven molecules. If compounds posses internal plane of symmetry, then it is said to be meso…

Q: CH CH, H Pd/C он CH,CHCH,CH, H,SO, Br "OCH,

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Q: OH 7. KMNO4 H3C- -CH3 H3C

A:

Q: b) CH, - CH=CH, + HCI c) CH,= CH-CH, + KMNO, + + MnO, + d) n(CH=CH-CH,) > t°,OH e) CH,=CH, + KMNO,…

A: The answer to the following question is-

Q: 1. CH,CH=CHCH, 3. BrFC=CHCH,

A:

Q: H. Ag,0. NAOH H;O* E F H,0, A LIAIH4 CH;(CH»)¡CN G Eter Raney Ni K H* + HSCH;CH;SH M

A: In the presence of Ag2O, NaOH, H­2O and heat, aldehyde undergoes oxidation.

Q: CH3 Br2 H2 a) b) Pd 1) BH3 H 2) H,O¬/NaOH 1) Hg(OAc),/H,O B 2) NaBH4

A: As alkenes have unsaturation and this unsaturated bond is quite labile, a number of reactions of…

Basics in Organic Reactions Mechanisms

In organic chemistry, the mechanism of an organic reaction is defined as a complete step-by-step explanation of how a reaction of organic compounds happens. A completely detailed mechanism would relate the first structure of the reactants with the last structure of the products and would represent changes in structure and energy all through the reaction step.

Heterolytic Bond Breaking

Heterolytic bond breaking is also known as heterolysis or heterolytic fission or ionic fission.  It is defined as breaking of a covalent bond between two different atoms in which one atom gains both of the shared pair of electrons. The atom that gains both electrons is more electronegative than the other atom in covalent bond. The energy needed for heterolytic fission is called as heterolytic bond dissociation energy.

Polar Aprotic Solvent

Solvents that are chemically polar in nature and are not capable of hydrogen bonding (implying that a hydrogen atom directly linked with an electronegative atom is not found) are referred to as polar aprotic solvents. Some commonly used polar aprotic solvents are acetone, DMF, acetonitrile, DMSO, etc.  

Oxygen Nucleophiles

Oxygen being an electron rich species with a lone pair electron, can act as a good nucleophile. Typically, oxygen nucleophiles can be found in these compounds- water, hydroxides and alcohols. 

Carbon Nucleophiles

We are aware that carbon belongs to group IV and hence does not possess any lone pair of electrons. Implying that neutral carbon is not a nucleophile then how is carbon going to be nucleophilic? The answer to this is that when a carbon atom is attached to a metal (can be seen in the case of organometallic compounds), the metal atom develops a partial positive charge and carbon develops a partial negative charge, hence making carbon nucleophilic.