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One of the reactions that occurs in polluted air in urban areas is 2NO2(3) + O3lg) → N2O5(3) + O2l3). Assume that a species with the formula NO3 is involved in the mechanism, and the observed rate law for the overall reaction is rate - k[NO2][031. Propose a mechanism for this reaction that includes the species NO3 and is consistent with the observed rate law. NO2(3) + O3(g) – NO3(g) + Ozlg) (fast) 4NO;G) – 2N¿O5(3) + O23) (slow) NO:G) + Oglg) → NO3(s) + O2lg) (slow) NO3(9) + NO2(g) – N2Os(G) (fast) NO2(3) + O3lg) → NO3lg) + O2ls) (fast) NO3(g) + NO2(3) – N;Os(3) (slow) NO2(3) + O3lg) → NOJG) + Ozlg) (slow) 4NO33) – 2N2O5(g) + O2lg) (fast)

One of the reactions that occurs in polluted air in urban areas is 2NO2(3) + O3lg) → N2O5(3) + O2l3). Assume that a species with the formula NO3 is involved in the mechanism, and the observed rate law for the overall reaction is rate - k[NO2][031. Propose a mechanism for this reaction that includes the species NO3 and is consistent with the observed rate law. NO2(3) + O3(g) – NO3(g) + Ozlg) (fast) 4NO;G) – 2N¿O5(3) + O23) (slow) NO:G) + Oglg) → NO3(s) + O2lg) (slow) NO3(9) + NO2(g) – N2Os(G) (fast) NO2(3) + O3lg) → NO3lg) + O2ls) (fast) NO3(g) + NO2(3) – N;Os(3) (slow) NO2(3) + O3lg) → NOJG) + Ozlg) (slow) 4NO33) – 2N2O5(g) + O2lg) (fast)

Chemistry: Principles and Practice
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.81QE: The gas-phase reaction of nitrogen monoxide with chlorine proceeds to form nitrosyl chloride....
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One of the reactions that occurs in polluted air in urban areas is 2NO2(3) + O3lg) – N2O5(3) + O2l3). Assume that a species with the formula NOz is involved in the mechanism, and the observed rate law for the overall reaction is rate - k[NO2][03). Propose a mechanism for this reaction that includes the species NO3 and is consistent with the observed rate law. NO2(9) + Oslg) – NO39) + O2l9) (fast) 4NO:(G) – 2N;O5() + Ozlg) (slow) NO2(3) + O3ls) – NO33) + O2lg) (slow) NO3(9) + NO2(s) – N2O5(g) (fast) NO2(3) + Os(g) – NO:6) + O2lg) (fast) NOgl) + NO2(3) – N2OsG) (slow) NO2(3) + Oslg) – NO3lg) + O2lg) (slow) 4NO3(3) – 2N2O5(3) + O2l3) (fast)
Transcribed Image Text:One of the reactions that occurs in polluted air in urban areas is 2NO2(3) + O3lg) – N2O5(3) + O2l3). Assume that a species with the formula NOz is involved in the mechanism, and the observed rate law for the overall reaction is rate - k[NO2][03). Propose a mechanism for this reaction that includes the species NO3 and is consistent with the observed rate law. NO2(9) + Oslg) – NO39) + O2l9) (fast) 4NO:(G) – 2N;O5() + Ozlg) (slow) NO2(3) + O3ls) – NO33) + O2lg) (slow) NO3(9) + NO2(s) – N2O5(g) (fast) NO2(3) + Os(g) – NO:6) + O2lg) (fast) NOgl) + NO2(3) – N2OsG) (slow) NO2(3) + Oslg) – NO3lg) + O2lg) (slow) 4NO3(3) – 2N2O5(3) + O2l3) (fast)
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