"One-pot" DCC (1.5 equiv) CH2CI2 (2mL) rt, 2h CF3CH,OH (4mL) Phl(OAc)2 (1.0 equiv) 5 minutes OH B Но NBoc D HN. `R1 R OHC CF3SO3H (2.0 equiv) 5 minutes A (1.5 equiv) R2 (2.0 equiv) H20 (5 mL) then aldehyde, 24h

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter14: Chromatography
Section: Chapter Questions
Problem 9P
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Find the structure of D with proper stereochemistry and mechanism. (Don't answer if you don't know stereochemistry and proper mechanism)

"One-pot"
DCC (1.5 equiv)
CH2CI2 (2mL)
rt, 2h
CF3CH,OH (4mL)
Phl(OAc)2 (1.0 equiv)
5 minutes
OH
B
но
NBoc
+
D
`R'
ОНС
CF3SO3H (2.0 equiv)
5 minutes
A
(1.5 equiv)
(2.0 equiv)
Н2о (5 mL)
then aldehyde, 24h
R2
Transcribed Image Text:"One-pot" DCC (1.5 equiv) CH2CI2 (2mL) rt, 2h CF3CH,OH (4mL) Phl(OAc)2 (1.0 equiv) 5 minutes OH B но NBoc + D `R' ОНС CF3SO3H (2.0 equiv) 5 minutes A (1.5 equiv) (2.0 equiv) Н2о (5 mL) then aldehyde, 24h R2
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