Only 98 a and b and c please

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter3: Mass Relations In Chemistry; Stoichiometry
Section: Chapter Questions
Problem 53QAP: Cyanogen gas, C2N2, has been found in the gases of outer space. It can react with fluorine to form...
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Only 98 a and b and c please
3.87 When 0,100 mol of carbon is burned in a closed vessel with
8.00 g of oxygen, how many grams of carbon dioxide can form?
Which reactant is in excess, and how many grams of it remain
after the reaction?
(c) If each oxygen atom represents 0.050 mol, how many
molecules of dichlorine monoxide were present before the
decomposition?
3.99 An intermediate step in the production of nitric acid involves
the reaction of ammonia with oxygen gas to form nitrogen mon-
oxide and water. How many grams of nitrogen monoxide can
form in the reaction of 485 g of ammonia with 792 g of oxygen?
3.88 A mixture of 0.0375 g of hydrogen and 0.0185 mol of oxy-
gen in a closed container is sparked to initiate a reaction. How
many grams of water can form? Which reactant is in excess, and
how many grams of it remain after the reaction?
3.100 Butane gas is compressed and used as a liquid fuel in dis-
posable cigarette lighters and lightweight camping stoves. Sup-
pose a lighter contains 5.50 mL of butane (d = 0.579 g/mL).
(a) How many grams of oxygen are needed to burn the butane
completely?
(b) How many moles of H,O form when all the butane burns?
(c) How many total molecules of gas form when the butane burns
completely?
3.101 Sodium borohydride (NaBH4) is used industrially in many
organic syntheses. One way to prepare it is by reacting sodium
hydride with gaseous diborane (B2H&). Assuming an 88.5% yield,
how many grams of NaBH, can be prepared by reacting 7.98 g of
sodium hydride and 8.16 g of diborane?
3.89 Aluminum nitrite and ammonium chloride react to form alu-
minum chloride, nitrogen, and water. How many grams of each
substance are present after 72.5 g of aluminum nitrite and 58.6 g
of ammonium chloride react completely?
3.90 Calcium nitrate and ammonium fluoride react to form cal-
cium fluoride, dinitrogen monoxide, and water vapor. How many
grams of each substance are present after 16.8 g of calcium nitrate
and 17.50 g of ammonium fluoride react completely?
3.91 Two successive reactions, A B and B C, have
yields of 73% and 68%, respectively. What is the overall percent
yield for conversion of A to C?
3.92 Two successive reactions, D E and E → F, have
yields of 48% and 73%, respectively. What is the overall percent
yield for conversion of D to F?
Comprehensive Problems
3.102 The mole is defined in terms of the carbon-12 atom. Use the
definition to find (a) the mass in grams equal to 1 atomic mass
unit; (b) the ratio of the gram to the atomic mass unit.
3.93 What is the percent yield of a reaction in which 45.5 g of
tungsten(VI) oxide (WO3) reacts with excess hydrogen gas to pro-
duce metallic tungsten and 9.60 mL of water (d = 1.00 g/mL)?
3.103 The first sulfur-nitrogen compound was prepared in 1835
and has been used to synthesize many others. In the early 1980s,
researchers made another such compound that conducts electric-
ity like a metal. Mass spectrometry of the compound shows a
molar mass of 184.27 g/mol, and analysis shows it to contain
2.288 g of S for every 1.000 g of N. What is its molecular
formula?
3.94 What is the percent yield of a reaction in which 200. g of
phosphorus trichloride reacts with excess water to form 128 g of
HCl and aqueous phosphorous acid (H,PO,)?
3.95 When 20.5 g of methane and 45.0 g of chlorine gas undergo
a reaction that has a 75.0% yield, what mass (g) of chloromethane
(CH.CI) forms? Hydrogen chloride also forms.
3.104 Hydroxyapatite, Cas(PO4)3(OH), is the main mineral
component of dental enamel, dentin, and bone. Coating the com-
pound on metallic implants (such as titanium alloys and stainless
steels) helps the body accept the implant. When placed in bone
voids, the powder encourages natural bone to grow into the void.
Hydroxyapatite is prepared by adding aqueous phosphoric acid
to a dilute slurry of calcium hydroxide. (a) Write a balanced
equation for this preparation. (b) What mass (g) of hydroxyapa-
tite could form from 100. g of 85% phosphoric acid and 100. g of
calcium hydroxide?
3.96 When 56.6 g of calcium and 30.5 g of nitrogen gas undergo
a reaction that has a 93.0% yield, what mass (g) of calcium nitride
forms?
Problems in Context
3.97 Cyanogen, (CN)2, has been observed in the atmosphere of
Titan, Saturn's largest moon, and in the gases of interstellar nebu-
las. On Earth, it is used as a welding gas and a fumigant. In its
reaction with fluorine gas, carbon tetrafluoride and nitrogen tri-
fluoride gases are produced. What mass (g) of carbon tetrafluo-
ride forms when 60.0 g of each reactant is used?
3.98 Gaseous dichlorine monoxide decomposes readily to chlo-
rine (green) and oxygen (red) gases.
3.105 Narceine is a narcotic in opium that crystallizes from solu-
tion as a hydrate that contains 10.8 mass % water and has a molar
mass of 499.52 g/mol. Determine x in narceine-xH,O.
3.106 Hydrogen-containing fuels have a "fuel value" based on
their mass % H. Rank the following compounds from highest fuel
value to lowest: ethane, propane, benzene, ethanol, cetyl palmitate
(whale oil, C3,H64O2).
ethane
propane
benzene
(a) Which scene best depicts the product mixture after the decom-
position?
(b) Write the balanced equation for the decomposition.
ethanol
Transcribed Image Text:3.87 When 0,100 mol of carbon is burned in a closed vessel with 8.00 g of oxygen, how many grams of carbon dioxide can form? Which reactant is in excess, and how many grams of it remain after the reaction? (c) If each oxygen atom represents 0.050 mol, how many molecules of dichlorine monoxide were present before the decomposition? 3.99 An intermediate step in the production of nitric acid involves the reaction of ammonia with oxygen gas to form nitrogen mon- oxide and water. How many grams of nitrogen monoxide can form in the reaction of 485 g of ammonia with 792 g of oxygen? 3.88 A mixture of 0.0375 g of hydrogen and 0.0185 mol of oxy- gen in a closed container is sparked to initiate a reaction. How many grams of water can form? Which reactant is in excess, and how many grams of it remain after the reaction? 3.100 Butane gas is compressed and used as a liquid fuel in dis- posable cigarette lighters and lightweight camping stoves. Sup- pose a lighter contains 5.50 mL of butane (d = 0.579 g/mL). (a) How many grams of oxygen are needed to burn the butane completely? (b) How many moles of H,O form when all the butane burns? (c) How many total molecules of gas form when the butane burns completely? 3.101 Sodium borohydride (NaBH4) is used industrially in many organic syntheses. One way to prepare it is by reacting sodium hydride with gaseous diborane (B2H&). Assuming an 88.5% yield, how many grams of NaBH, can be prepared by reacting 7.98 g of sodium hydride and 8.16 g of diborane? 3.89 Aluminum nitrite and ammonium chloride react to form alu- minum chloride, nitrogen, and water. How many grams of each substance are present after 72.5 g of aluminum nitrite and 58.6 g of ammonium chloride react completely? 3.90 Calcium nitrate and ammonium fluoride react to form cal- cium fluoride, dinitrogen monoxide, and water vapor. How many grams of each substance are present after 16.8 g of calcium nitrate and 17.50 g of ammonium fluoride react completely? 3.91 Two successive reactions, A B and B C, have yields of 73% and 68%, respectively. What is the overall percent yield for conversion of A to C? 3.92 Two successive reactions, D E and E → F, have yields of 48% and 73%, respectively. What is the overall percent yield for conversion of D to F? Comprehensive Problems 3.102 The mole is defined in terms of the carbon-12 atom. Use the definition to find (a) the mass in grams equal to 1 atomic mass unit; (b) the ratio of the gram to the atomic mass unit. 3.93 What is the percent yield of a reaction in which 45.5 g of tungsten(VI) oxide (WO3) reacts with excess hydrogen gas to pro- duce metallic tungsten and 9.60 mL of water (d = 1.00 g/mL)? 3.103 The first sulfur-nitrogen compound was prepared in 1835 and has been used to synthesize many others. In the early 1980s, researchers made another such compound that conducts electric- ity like a metal. Mass spectrometry of the compound shows a molar mass of 184.27 g/mol, and analysis shows it to contain 2.288 g of S for every 1.000 g of N. What is its molecular formula? 3.94 What is the percent yield of a reaction in which 200. g of phosphorus trichloride reacts with excess water to form 128 g of HCl and aqueous phosphorous acid (H,PO,)? 3.95 When 20.5 g of methane and 45.0 g of chlorine gas undergo a reaction that has a 75.0% yield, what mass (g) of chloromethane (CH.CI) forms? Hydrogen chloride also forms. 3.104 Hydroxyapatite, Cas(PO4)3(OH), is the main mineral component of dental enamel, dentin, and bone. Coating the com- pound on metallic implants (such as titanium alloys and stainless steels) helps the body accept the implant. When placed in bone voids, the powder encourages natural bone to grow into the void. Hydroxyapatite is prepared by adding aqueous phosphoric acid to a dilute slurry of calcium hydroxide. (a) Write a balanced equation for this preparation. (b) What mass (g) of hydroxyapa- tite could form from 100. g of 85% phosphoric acid and 100. g of calcium hydroxide? 3.96 When 56.6 g of calcium and 30.5 g of nitrogen gas undergo a reaction that has a 93.0% yield, what mass (g) of calcium nitride forms? Problems in Context 3.97 Cyanogen, (CN)2, has been observed in the atmosphere of Titan, Saturn's largest moon, and in the gases of interstellar nebu- las. On Earth, it is used as a welding gas and a fumigant. In its reaction with fluorine gas, carbon tetrafluoride and nitrogen tri- fluoride gases are produced. What mass (g) of carbon tetrafluo- ride forms when 60.0 g of each reactant is used? 3.98 Gaseous dichlorine monoxide decomposes readily to chlo- rine (green) and oxygen (red) gases. 3.105 Narceine is a narcotic in opium that crystallizes from solu- tion as a hydrate that contains 10.8 mass % water and has a molar mass of 499.52 g/mol. Determine x in narceine-xH,O. 3.106 Hydrogen-containing fuels have a "fuel value" based on their mass % H. Rank the following compounds from highest fuel value to lowest: ethane, propane, benzene, ethanol, cetyl palmitate (whale oil, C3,H64O2). ethane propane benzene (a) Which scene best depicts the product mixture after the decom- position? (b) Write the balanced equation for the decomposition. ethanol
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