ow did Werner first explain bonding in complexes Tetraaminecarbonatocobalt(III) nitrate and pentaamminechlorocobalt(II)chloride

Q: Provide a name for the following complex ion:[AuF4]^-

A: Naming an inorganic complex ionRules to follow,Name all the ligands first in alphabetical order and…

Q: Explain the effect of functional groups on the structure of the ligand (A) by considering HSAB on…

A: Here, we need to explain the formation of complex B by using ligand A by employing concept of Hard…

Q: Fill in the blanks : (i) When a ligand has a two-complexing or donor group in its structure, it is…

A: In this question, we have to find out the correct answer of given problem by the help of the…

Q: What is the formula of the complex cation? + NH3 H3N 'CI NH3 trans-[Co(NH,),CI,] cis-[CoCI,(NH,),I…

A: Which of the given option is correct--

Q: d. Fig. 10.41 The occupation of energy levels in a d'octahedral complex.

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Q: What is the LFSE for the [Re(H2O)6]3+complex, knowing that ΔΔo =  33000 cm-1 and P= 15000 cm-1 ?

A: Electron configuration of Re is  [Xe] 4f14 5d5 6s2 When the metal Re forms  octahedral complex with…

Q: The factor determining the mechanism observed in the substitution reactions of square plane…

A: Substitution reactions in coordination complexes are the reactions in which one ligand in a complex…

Q: 14. In the determination of Kf for the iron thiocyanate complex, what is the color of the complex?…

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Q: Which of the following is responsible for the chelate effect exhibited by multidentate ligands? a.…

A: This question is related to coordination Chemistry. Coordination complexes are the molecules in…

Q: Construct an MO correlation diagram for the complex ion[Ni(NH3)6]2+ and populate the orbitals with…

A: The atomic number of Ni is 28. The oxidation state of Ni in the complex [Ni (NH3)6]2+ is +2. The…

Q: In the octahedral field, dx2-v2 and d,2 are denoted as e, orbitals with the s-symmetry while dxy,…

A: In octahedral field, the molecular orbital diagram in different kind of ligand is different.…

Q: (a) Give systematic names for the following formulas: - [Co(N3)(NH3)s]SO4 - KĄ[Fe(CN);ONO] -…

A: The nomenclature of the coordination complexes are  given below

Q: Explain the stability of the complexes TiCl62- and [Zn(en)3]2+

A: TiCl62-  is less stable than [Zn(en)3]+2 because Ethylene Di ammine is bidentate ligand so it will…

Q: At 580 nm, the wavelength of maximum absorption, the complex Fe(SCN)2+ has a molar absorptivity of…

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Q: Which among the following complexes has the highest value of spin magnetic moment?     a.…

A: Spin magnetic moment (s) = √(n(n+2)) n = number of unpaired electron ->As unpaired electron…

Q: 3. The coordination geometries around the nickel atom in the nominally six-coordinate complexes…

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Q: Jahn-Teller distortions are often encountered with а. octahedral complexes of dº and high o spin d4…

A: Jahn teller distortion occurs in those complexes which has unpaired electron in t2g or eg orbital ie…

Q: When the K[PtCl3(C2H4)] complex obeys the 18 electron rule according to the electron pair donor…

A: The electron-pair donor method of counting the electrons is also known as the ionic method. The…

Q: Shown below is an abbreviated spectrochemical series arranged according to decreasing ligand field…

A: According to the crystal field theory, in the presence of the ligand field, the five d-orbitals of…

Q: [COCI (NH3) 5] C12 Examine whether the complex obeys the effective atomic number rule.

A: The EAN rule means effective atomic number rule. When an atom obeys the EAN rule then it must attain…

Q: 13. A complex ion has been observed which starts with a violet color with six aqua ligands attached.…

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Q: [FeL6]* complex (L indicates a monodentate ligand) has a magnetic m approximately 1.73 B.M. a) What…

A: The electronic configuration is given by, [FeL6]3- i.e. Fe 3+: 18(Ar) 4s0 3d5

Q: The metal ion, M2+, formed a paramagnetic tetrahedral complex [MJ4]2+, having three unpaired…

A: The given metal ion is M2+

Q: How did conductivity help to confirm the structure of complexes [Co(NH3)4CO3]NO3 and [Co(NH3)5Cl]Cl2

A: The conductivity measurement of a coordination compoud [Co(NH3)4CO3]NO3  shows that it dissociates…

Q: Determine the number of stereoisomers for square-planar metal complex: [PtCl2(en)]? en…

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Q: 23.58: d,e

A: The central metal ion in the complex [Cr(NH3)4Br2]ClO4  is Cr. The ClO4 atoms are written out of the…

Q: Sketch the structure of all isomers of the complexes listed below.…

A: Diiododinitritodiaquapalladium(IV) - Type Ma2b2c2  = 5 isomers Bromochlorodiaquadiamminecobalt(III)…

Q: The factor determining the mechanism observed in the substitution reactions of square plane…

A: here, for the nucleophilic substitution reaction Sn2 for the inorganic reaction mechanism  yes, This…

Q: 13. Using d-orbital splitting diagrams, please determine which of following complexes can exhibit…

A: Jahn-Teller effect refers to the distortion which occurs in the non-linear molecule. Due to this…

Q: a) describe 4 factors that influence the sizes of crystal field splitting sun a transition metal…

A: According to Q&A guidelines of Bartleby, we are supposed to answer only the first question out…

Q: Each of a series of ligands, A, B and C can bind Li' ions. The values of AH (KJmol') for the…

A: The stability of coordination complex is an important factor that decides the stability and…

Q: B. Čomplexes of the Copper(II) Ion Ligand ©Color Formula of Complex OEffect of OH- NH3…

A: As Cu2+  system is d9 system. It undergo J-T distortion in octahedral chemistry  When there is OH -…

Q: catahedral” Cu (II) complexes are often described as having a (4+2)- coordination pattern. Suggest…

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Q: Write the valence electron configuration for the cobalt ions in the complexes [CoCl4]2- and draw…

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Q: a) Draw the lewis structure of the nitrate ion and discuss its potential to serve as an ambidentate…

A: Ambidentate Ligand : This are one type of monodentate ligands having two different donar atoms, that…

Q: After the NH3 molecules acted as Bronsted bases in the reaction with aqueous HCl they became NH4 +…

A: Concept:  A Ligands can be a ions or neutral molecules that bond to a central metal atom or ion.…

Q: connect these complexes using ligand exchange  reactions and use it to solve a national problem.…

A: Find the complete solution given below

Q: The values for lmax for complex A and B are 512 nm and 650 nm respectively.  A has the structure…

A: 1)

Q: 6) Complexes with five d electrons (d) are sometimes tetrahedral and sometimes octahedral. Consider…

A: Given is  ∆o =11000 cm-1 And we have to determine ∆t Also we know that  ∆t = 4/9 ∆o

Q: The correct systematic name for the complex [Mn(NCS)3(OH₂) (Ox)] is O tris(thiocyanato-KN)…

A: k is used to specify which ligand atoms are bonding to the central atom. Oxidation state of Mn in…

Q: A shortcut to finding optical isomers is to see if the complexhas a plane of symmetry—a plane…

A: Optically active compounds should not have a plane of symmetry in them. These molecules has the…

Q: When MCl4(NH3)2 is dissolved in water and treated withAgNO3, 2 mol of AgCl precipitates immediately…

A: When MCl4(NH3)2 is dissolved in water and treated withAgNO3, 2 mol of AgCl precipitates immediately…

Q: (b) Discuss the electric quadruple splitting in Mössbauer spectroscopy. Explain how this is helpful…

A: Answer - Quadrupole splitting - Quadrupole splitting is measured as the separation between these two…

Q: The complex Mo(CO)3(NCC2H5)3 has the infrared spectrum shown below. Is this complex more likely the…

A: The mentioned complex is Mo(CO)3(NCC2H5)3

Q: For each of the following complexe ate) and give its magnetic propertie 3. [Fe(NH,),J²* [Cr(CO),J*

A: Concept is based on spectrochemical series. It decides the spin of ligands.

Q: Broad absorption bands are characteristics of the spectra of transition metal complexes. Discuss the…

A: Transition metal atoms give broad peaks in spectra due to vibronic coupling i.e vibration of bonds…

Q: Write the Werner’s formula for the following coordination compounds: (a)…

A: a) The name of the compound given is Tetraamminediaquacobalt(III) chloride.

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.