Answered: d. Fig. 10.41 The occupation of energy…

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d. Fig. 10.41 The occupation of energy levels in a d'octahedral complex.

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter21: Structure And Bonding In Solids

Section: Chapter Questions

Problem 36P

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Question

Experimentally, it is found that the value of DO varies with the chemical nature of the ligand according to the spectrochemical series: S2− < Cl− < OH− ≈ RCO2− < H2O ≈ RS− < NH3 ≈ imidazole (the side chain of histidine) < CN− < CO. (a) Draw an energy level diagram like those in Fig. 10.41 showing the configuration of the d electrons on the metal ion in [Fe(OH2)6]3+ and [Fe(CN)6]3−.

d.
Fig. 10.41 The occupation of
energy levels in a d’ octahedral
complex.

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