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- Which reagent(s) sequence(s) is/are optimum for preparing butanoic acid from 1-propanol? i. K2Cr2O7 in acidii. (1) PBr3; (2) NaCN; (3) H2O; (4) [H+] iii. (1) NaCN; (2) H2O; (3) [H+]iv. LiAlH4The following reactions are unlikely to provide the indicated product in high yield. What is wrong with each?Calculate ΔSsys° (J/K) for the catalytic hydrogenation of acetylene to ethane: C2H2(g) + H2(g) → C2H4(g) Substance S° (J/K·mol) C2H2(g) 200.8 H2(g) 130.58 C2H4(g) 219.4
- Giventhefollowingsetofreactionsandtheirenthalpies,drawtheBorn-Habercyclefortheformationof LiCl(s)anddeterminethelatticeenergyforLiCl.Reactions:H (in kJ)(1)Li(s)Li(g);Hs= 161;(2) Li(g)Li+(g)+e–;IE= 520;(3) ½Cl2(g)Cl(g);½BE =121.5;(4)Cl(g)+ e–Cl–(g);EA= –349;(5)Li+(g)+ Cl–(g)LiCl(s);UL= ?(UL= latticeenergy)(6) Li(s)+ ½ Cl2(g)LiCl(s);Hof=–408.6._______________________________________________________________________________Plese answer D, E AND F ONLY, Thank You.The diazotization of aniline first involves the formation of NO+ (nitrosonium ion) by the dehydration of nitrous acid with sulfuric acid. The aniline nitrogen then acts as a nucleophile and eventually loses water. Propose a mechanism for the formation of the dizaonium salt of aniline. Use curved arrows to show all electron movement.
- Acid-catalyzed hydrolysis of a nitrile to give a carboxylic acid occurs by initial protonation of the nitrogen atom, followed by nucleophilic addition of water. Review the mechanism of base-catalyzed nitrile hydrolysis in Section 20-7 and then predict the products for each reaction below and write all of the steps involved in the acid-catalyzed reaction, using curved arrows to represent electron flow in each step.Polyimides with the structure shown are used as coatings on glass and plastics to improve scratch resistance. How would you synthesize a polyimide? (See Problem 21-39.)Phenols (ArOH) are relatively acidic, and the presence of a substituent group on the aromatic ring has a large effect. The pKa of unsubstituted phenol, for example, is 9.89, while that of p-nitrophenol is 7.15. Draw resonance structures of the corresponding phenoxide anions and explain the data.