Polydentate ligands can vary in the number of coordi- nation positions they occupy. In each of the following, identify the polydentate ligand present and indicate the probable number of coordination positions it occupies: (a) [Co(NH3)4(0-phen)JCI3 (b) [Cr(C204)(H20),]Br (c) [Ca(EDTA)]²- (d) [Zn(en),](CIO4)2

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 121QRT: The glycinate ion (gly) is H2NCH2CO2. It can act as a ligand coordinating through the nitrogen and...
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For each of the following polydentate ligands, determine (i)
the maximum number of coordination sites that the ligand
can occupy on a single metal ion and (ii) the number and
type of donor atoms in the ligand: (a) ethylenediamine
(en), (b) bipyridine (bipy), (c) the oxalate anion (C2O42-),
(d) the 2- ion of the porphine molecule (Figure ),
(e) [EDTA4]-.

Polydentate ligands can vary in the number of coordi-
nation positions they occupy. In each of the following,
identify the polydentate ligand present and indicate the
probable number of coordination positions it occupies:
(a) [Co(NH3)4(0-phen)JCI3
(b) [Cr(C204)(H20),]Br
(c) [Ca(EDTA)]²-
(d) [Zn(en),](CIO4)2
Transcribed Image Text:Polydentate ligands can vary in the number of coordi- nation positions they occupy. In each of the following, identify the polydentate ligand present and indicate the probable number of coordination positions it occupies: (a) [Co(NH3)4(0-phen)JCI3 (b) [Cr(C204)(H20),]Br (c) [Ca(EDTA)]²- (d) [Zn(en),](CIO4)2
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