Predict the major products that result when cyclo- hexanone is reacted with each of the following. a) excess CH,OH and trace HCl b) NH,NH,, then Kt-BuO and heat c) NH,OH

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter22: Carbonyl Alpha-substitution Reactions
Section22.SE: Something Extra
Problem 40AP: Base treatment of the following , -unsaturated carbonyl compound yields an anion by removal of H+...
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16.14 Predict the major products that result when cyclo-
hexanone is reacted with each of the following.
a) excess CH,OH and trace HCI
b) NH,NH,, then Kt-BuO and heat
c) NH,OH
d) HOCH,CH,CH,OH and trace HCI
e) CH,CH,CH,NH, and ACOH
) HSCH,CH,SH and TiCl,
g pyrrolidine and acetic acid
h) PHCH,CH(OH)CO,H and trace HCI
) HSCH,CHCH,OH and trace H,SO,
j) catechol and H,SO4
k) PHNH,, ACOH, and NaBH,CN
Cmations.
Transcribed Image Text:16.14 Predict the major products that result when cyclo- hexanone is reacted with each of the following. a) excess CH,OH and trace HCI b) NH,NH,, then Kt-BuO and heat c) NH,OH d) HOCH,CH,CH,OH and trace HCI e) CH,CH,CH,NH, and ACOH ) HSCH,CH,SH and TiCl, g pyrrolidine and acetic acid h) PHCH,CH(OH)CO,H and trace HCI ) HSCH,CHCH,OH and trace H,SO, j) catechol and H,SO4 k) PHNH,, ACOH, and NaBH,CN Cmations.
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