Qs3. Tell how you would use the proton NMR and IR spectra to distinguish between ethyl benzoate and 4- ethylbenzoic acid (drawing the structures will help you a lot). You can draw a schematic NMR spectrum for each compound, or simply list the peaks that shall be present (including integration and multiplicity).

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter14: Chromatography
Section: Chapter Questions
Problem 6P
icon
Related questions
Question

I really need help with #3 and #4

Qs3. Tell how you would use the proton NMR and IR spectra to distinguish between ethyl benzoate and 4-
ethylbenzoic acid (drawing the structures will help you a lot). You can draw a schematic NMR spectrum for
each compound, or simply list the peaks that shall be present (including integration and multiplicity).
Qs4. Provide the structure of the compound that being a liquid does not dissolve in water. However, under
acidic conditions and at elevated temperature it readily dissolves in water with the formation of water-
insoluble product. This product can be dissolved in water only at boiling or in a presence of a base. The 13C
NMR of the reactant shows 7 signals. Its 1H NMR and IR spectra are below.
100-
80-
60-
40-
* 20-
4.4 4.35
1.4 1.35
4000
3000
2000
1500
1000
500
8.
7
6
3
2
Wavenumbers (cm-1)
Chemical shift (ppm)
For a bigger picture (and integration values), see the next page.
Transcribed Image Text:Qs3. Tell how you would use the proton NMR and IR spectra to distinguish between ethyl benzoate and 4- ethylbenzoic acid (drawing the structures will help you a lot). You can draw a schematic NMR spectrum for each compound, or simply list the peaks that shall be present (including integration and multiplicity). Qs4. Provide the structure of the compound that being a liquid does not dissolve in water. However, under acidic conditions and at elevated temperature it readily dissolves in water with the formation of water- insoluble product. This product can be dissolved in water only at boiling or in a presence of a base. The 13C NMR of the reactant shows 7 signals. Its 1H NMR and IR spectra are below. 100- 80- 60- 40- * 20- 4.4 4.35 1.4 1.35 4000 3000 2000 1500 1000 500 8. 7 6 3 2 Wavenumbers (cm-1) Chemical shift (ppm) For a bigger picture (and integration values), see the next page.
100-
80-
60-
40-
৪ 20-
4.4 4.35
1.4 1.35
0-
4000
3000
2000
1500
1000
500
8
7
6
4.
3
2
1
Wavenumbers (cm-1)
Chemical shift (ppm)
For a bigger picture (and integration values), see the next page.
100
80-
40-
20-
4000
3000
2000
1500
1000
500
Wavenumbers (cm-1)
2H
4.4 4.35
1.4 1.35
8 7
5
4
1
Chemical shift (ppm)
% Transmittance
% Transmittance
60
Transcribed Image Text:100- 80- 60- 40- ৪ 20- 4.4 4.35 1.4 1.35 0- 4000 3000 2000 1500 1000 500 8 7 6 4. 3 2 1 Wavenumbers (cm-1) Chemical shift (ppm) For a bigger picture (and integration values), see the next page. 100 80- 40- 20- 4000 3000 2000 1500 1000 500 Wavenumbers (cm-1) 2H 4.4 4.35 1.4 1.35 8 7 5 4 1 Chemical shift (ppm) % Transmittance % Transmittance 60
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 1 images

Blurred answer
Knowledge Booster
Green Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Appl Of Ms Excel In Analytical Chemistry
Appl Of Ms Excel In Analytical Chemistry
Chemistry
ISBN:
9781285686691
Author:
Crouch
Publisher:
Cengage
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Fundamentals Of Analytical Chemistry
Fundamentals Of Analytical Chemistry
Chemistry
ISBN:
9781285640686
Author:
Skoog
Publisher:
Cengage