Question 1 Account for the relative values of the rate constants for the following outer sphere electron-transfer reactions by considering reorganization energy and driving force. Be sure to state which reactions have AG° = 0. Reaction Reactants k/ dm³ mol1 s1 [Ru(NH3)6]3* + [Ru(NH3)6]²+ [Co(NH3)6]3* + [Ru(NH3)6]?* [Co(NH3)6]³* + [Co(NH3)G]²* 104 II 102 II 106

Question 1 Account for the relative values of the rate constants for the following outer sphere electron-transfer reactions by considering reorganization energy and driving force. Be sure to state which reactions have AG° = 0. Reaction Reactants k/ dm³ mol1 s1 [Ru(NH3)6]3* + [Ru(NH3)6]²+ [Co(NH3)6]3* + [Ru(NH3)6]?* [Co(NH3)6]³* + [Co(NH3)G]²* 104 II 102 II 106

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter11: Chemical Kinetics: Rates Of Reactions

Section11.3: Rate Law And Order Of Reactions

Problem 11.5PSP

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