R .R allylic position benzylic position Benzylic cations, anions, and radicals are all more stable than simple alkyl intermediates.

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter19: Eas: Electrophilic Aromatic Substitution
Section: Chapter Questions
Problem 33E
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A benzene ring alters the reactivity of a neighboring group in the so-called “benzylic” position, similarly to how a double bond alters the reactivity of groups in the “allylic” position. Benzylic cations, anions, and radicals are all more stable than simple alkyl intermediates.

a) Use resonance structures to show the delocalization of the positive charge, negative charge,
and unpaired electron of the benzyl cation, anion, and radical.

R
allylic position
benzylic position
Benzylic cations, anions, and radicals are all more stable than simple alkyl intermediates.
Transcribed Image Text:R allylic position benzylic position Benzylic cations, anions, and radicals are all more stable than simple alkyl intermediates.
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