Answered: Reactions Mechanism Major Product…

Reactions Mechanism Major Product Mechanism Minor Product (SN1, SN1, E1, E2) (SN1, SN1, E1, E2) t-BUOK t-BUOH, 50°C Br CH,CO, CH,CO,H, 50°C 3-Chloropentane 25°C (S)-3-Bromo-3-methylhexane - MeOH

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter10: Oxidation And Reduction

Section: Chapter Questions

Problem 4CTQ

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Concept explainers

Reactions at the Alpha Carbon Atom

The position next to the ketone or aldehyde functional group is termed as alpha position and the reaction which occurs at alpha position is called alpha substitution reaction. In an alpha substitution reaction, the alpha proton atom is substituted by an electrophile by the formation of an enol intermediate or enolate ion intermediate. Most of the carbonyl compounds go through an alpha substitution reaction.

Question

Reactions
Mechanism
Major Product
Mechanism
Minor Product
(SN1, SN1, E1, E2)
(SN1, Sn1, E1, E2)
t-BUOK
t-BUOH, 50°C
Br
CH,CO,
CH;CO,H, 50°C
3-Chloropentane
25°C
(S)-3-Bromo-3-methylhexane -
MeOH

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