ReferencesUse the References to access important values if needed for this question.The average bond order is the number of bonds between two atoms taking into account resonance.Draw a Lewis structure for nitryl chloride and answer the questions below.1. There areequivalent Lewis structures for NO,CI(number)2. The average N O bond order ishttps://als-asp.cengage.info/als-asp/takeType here to searchFLV

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Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter3: Atomic Shells And Classical Models Of Chemical Bonding

Section: Chapter Questions

Problem 67P

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Please anwser the following it’s just naming structures. Thank u so much ??
The attractive force between two ions in Na20, Fc is 8.64x10-9N. What is the bond length a0 (in nm) given that valence of the charged Na+ is Z1=+1, for O-, is Z2 =-2, the charge of a single electron q is 0.16x10-18 C and the proportionality constant k0=9x109 V.m/C? Note that K=k0(Z1q)(Z2q) and that 1 V.C = 1 J.
provide the fllowing information including the lewis structure and the 3d sketch for NO2- and BrF3
The molecular ion S3N3 has the cyclic structure All SN bonds are equivalent. (a) Give six equivalent resonance hybrid Lewis diagrams for this molecular ion. (b) Compute the formal charges on all atoms in the molecular ion in each of the six Lewis diagrams. (c) Determine the charge on each atom in the polyatomic ion, assuming that the true distribution of electrons is the average of the six Lewis diagrams arrived at in parts (a) and (b). (d) An advanced calculation suggests that the actual charge resident on each N atom is 0.375 and on each S atom is +0.041 . Show that this result is consistent with the overall +1 charge on the molecular ion.
The percent ionic character of the bonds in several interhalogen Molecules (as estimated from their measured dipole moments and bond lengths) are ClF (11%), BrF(15%), BrCl (5.6%), ICl(5.8%), and IBr (10%). Estimate the percent ionic characters for each of these molecules, using the equation in Problem 37, and compare them with the given values.
Calculate the lattice energy of CaCl2 using a Born-Haber cycle and data from Appendices F and L and Table 7.5. TABLE 7.5 First, Second, and Third Ionization Energies for the Main Group Elements in Periods 24 (kJ/mol)
A compound is being tested for use as a rocket propellant. Analysis shows that it contains 18.54% F, 34.61% Cl, and 46.85% O. (a) Determine the empirical formula for this compound. (b) Assuming that the molecular formula is the same as the empirical formula, draw a Lewis diagram for this molecule. Review examples elsewhere in this chapter to decide which atom is most likely to lie at the center. (c) Use the VSEPR theory to predict the structure of the molecule from part (b).
Ozone (O3) has a nonzero dipole moment. In the molecule of O3 , one of the oxygen atoms is directly bonded to the other two, which are not bonded to each other. (a) Based on this information, state which of the following structures are possible for the ozone molecule: symmetric linear, nonsymmetric linear (for example, different OO bond lengths), and bent. (Note: Even an OO bond can have a bond dipole if the two oxygen atoms are bonded to different atoms or if only one of the oxygen atoms is bonded to a third atom.) (b) Use the VSEPR theory to predict which of the structures of part (a) is observed.
Draw the Lewis electron dot structures for these molecules, including resonance structures where appropriate: (a) CS32 (b) CS2 (c) CS (d) predict the molecular shapes for CS32 and CS2 and explain how you arrived at your predictions
Complete the table on next page.
Discuss the nature of the bonding in the nitrate ion (NO3) . Draw the possible Lewis resonance diagrams for this ion. Use the VSEPR theory to determine the steric number, the hybridization of the central N atom, and the geometry of the ion. Show how the use of resonance structures can be avoided by introducing a de-localized MO. What bond order is predicted by the MO model for the NO bonds in the nitrate ion?
Sulfuric acid is prepared by oxidizing sulfur to sulfur dioxide and then to sulfur trioxide. Although sulfur trioxide reacts with water to form sulfuric acid it forms a mist of find droplets of H2 S04 with water vapor that is hard to condense. Instead sulfur trioxide is first dissolved in 98% sulfuric acid to form oleum. On treatment with water concentrated sulfuric acid can be generated. Write equations for all the steps and draw Lewis structures of sulfuric acid and oleum.

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