An elusive intermediate of atmo spheric reactions of HONO may be nitrosyl O-hydroxide, HOON. Electronic structure calculations seem to indicate that HOON is best represented by a combination of three resonance structures, with major contribution from a radical-pair structure (involving HO and NO rad icals), significan t contribution from a molecular structure, and a small contribution from an ion-pair structure (involving HO- and NO+ ions). Use the information to represent the structure of HOON in terms of these three resonance structures.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter3: Atomic Shells And Classical Models Of Chemical Bonding
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Problem 38P: The percent ionic character of the bonds in several interhalogen Molecules (as estimated from their...
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An elusive intermediate of atmo spheric reactions of HONO may be nitrosyl O-hydroxide, HOON. Electronic structure calculations seem to indicate that HOON is best represented by a combination of three resonance structures, with major contribution from a radical-pair structure (involving HO and NO rad icals), significan t contribution from a molecular structure, and a small contribution from an ion-pair structure (involving HO- and NO+ ions). Use the information to represent the structure of HOON in terms of these three resonance structures.

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