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- Please refer to the images as much as you need to. For the following hydrocarbons, pick out 5 wavenumbers for each hydrocarbon, and give it its probable assignment for its structure. You may find this link useful: https://www.sigmaaldrich.com/US/en/technical-documents/technical-article/analytical-chemistry/photometry-and-reflectometry/ir-spectrum-table o-xylene (cm-1) : 985.76, 1021.06, 1052.51, 1119.30, 1383.43, 1465.62, 1495.11, 1604.66, 2859.82, 2874.76, 2922.19, 2937.08, 2968.08, 3016.57, 3049.67, 3063.02, 3105.51 m-xylene (cm-1) : 876.16, 904.28, 1039.26, 1094.05, 1169.56, 1376.70, 1397.17, 1458.12, 1491.51, 1538.93, 1557.96, 1591.83, 1612.18, 1652.69, 2730.72, 2863.59, 2920.44, 2944.72, 3015.77, 3104.24 p-xylene (cm-1) :1023.01, 1042.16, 1102.92, 1119.19, 1219.51, 1378.51, 1455.91, 1515.82, 1557.92, 1631.57, 1889.80, 2732.29, 2868.22, 2921.93, 2976.07, 2999.25, 3018.79, 3044.59, 3093.20, 3133.55, 3134.26The protein haemerythrin (Her) is responsible for binding and carrying O2 in some invertebrates. Each protein molecule has two Fe2+ ions that are in very close proximity and work together to bind one molecule of O2, form ing an Fe2O2 group. (a) The Raman spectrum of oxygenated haemerythrinobtained with laser excitation at 500 nm has a band at 844 cm-1 which has been attributed to the O-O stretching mode of bound 16O2. Why is Raman spectroscopy and not infrared spectroscopy the method of choice for the study of the binding of O2 to haemerythrin? (b) Proof that the 844 cm-1band in the Raman spectrum of oxygenated haemerythrin arises from a bound O2 species may be obtained by conducting experiments on samples of haemerythrin that have been mixed with 18O2, instead of 16O2 . Predict the fundamental vibrational wavenumber of the 18O-18O stretching mode in a sample of haemerythrin that has been treated with 18O2. (c) The fundamental vibrational wavenumbers for the O-O stretching modes of O2,…Remote spectroscopy is a powerful technique that allows for the non-destructive analysis of the physical and chemical properties of various materials and compounds. There are several types of remote spectroscopy, including reflectance, Raman, infrared, ultraviolet-visible, fluorescence, X-ray, terahertz, and time-resolved spectroscopy, each with its own unique advantages and applications. Explain all of them, including pictures for each, and sources. Please explain how they are used(i.e the equiment being used etc), and the science behind them.
- Calculate the resolution required to resolve the following peaks; i) CH3N+ (MW = 28.0187) and N2+ (MW = 28.0061) ii) C2H4+ (MW = 28.0313) and CO+ (MW = 27.9949) iii) C3H7N3+ (MW = 85.0641) and C5H9O+ (MW = 85.0653) iv) 116Sn+ (At W = 115.90219) and 232Th2+ (At W = 232.03800)How to find the signal-to-noise ratio from data given? How many measurements would have to be averaged to obtain a S/N of 500? Explanation for each step will be greatly appreciated.How to get coupling constants from this spectra. Values at the top are in ppm. The instrument is 300 MHz.
- How do I solve for [FeSCN2+] heres the formula they provided me and my data but I would like steps on how to solve it and what data I should be using to solve for it u can use any fake numbers you need to help me understand ! I'm confused only by the absorbance part , what number am I using for the absorbance? Is it Fe3+ added to ScN- absorbance values ? also e = 202 and L = 1.0When analyzing a selution component by UV-visible spectrophotometry. we prepare solutions with a range of concentrations by serial dilution. Why do we need to analyze a range of solutions? To allow multiple determinations of absorbance at different wavelengths and different concentrations To provide more than one determination of absorbance for a given concentration To see how absorbance varies with concentration To ensure that the linear relationship between absorbarce and concentrasion is velid for a range of concentrations.A Raman spectrum of undoped GaAs at room temperature is performed with a 514.5 nm laser. The spectrum of scattered light exhibits peaks at wavelengths of 507.1 nm and 591.6 nm due to interaction of the incident light with LO phonons. Calculate the LO phonon frequency and the ratio of the intensity of scattered light at 507.1 nm to that at 591.6 nm.
- Describe how to prepare adulterated palm oil samples before analysing it with Raman spectrometer. Also the describe the process how the Raman spectrometer will analyze the adulterated palm oil samplesDescribe how you will use the Raman spectroscopy to gain qualitative and quantitative information on Sudan IV dye in adulterated palm oil. Explain basis of analytical protocol.Give a detailed explanation of how Raman spectroscopy protocol will be used to process a sample of palm oil adulterated with Sudan IV