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:S-H :0: DD ? not | 10 S. O: e H DD ? not 0: DD ? not CI-CI: DD ? not N: :CI-F: DD ? not N :i-F: DD ? not :ö: DD ?

:S-H :0: DD ? not | 10 S. O: e H DD ? not 0: DD ? not CI-CI: DD ? not N: :CI-F: DD ? not N :i-F: DD ? not :ö: DD ?

Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter5: Gases, Liquids, And Solids
Section: Chapter Questions
Problem 5.72P
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Determining DD or not

Dipole-Dipole IeFs (DD) • Polar molecules stick with opposite ends of their dipoles. +8 8-+0 8- H= 1,9 D *... +8 8- Like ions, but more +8 8- DD +8 ... weakly (partial 8+, 8–). 8- → Find molecular polarity = predict DD: +8 :S-H :O: DD ? not | 100- b.p. °C ↑ Strong er IeFs H DD ? not :O: → b.p. grows with DDT 0:0 0: DD ? not H3C H3C" H. CH2 CH3 :CI-Cl: DD ? not N: 0- H3Ċ :Ci-F: DD ? not N H3C -40- O H3C-CI: CH3 H, D :I-F: DD? not :0: DD ? not 0. 2. 4 :ZEU-C
Transcribed Image Text:Dipole-Dipole IeFs (DD) • Polar molecules stick with opposite ends of their dipoles. +8 8-+0 8- H= 1,9 D *... +8 8- Like ions, but more +8 8- DD +8 ... weakly (partial 8+, 8–). 8- → Find molecular polarity = predict DD: +8 :S-H :O: DD ? not | 100- b.p. °C ↑ Strong er IeFs H DD ? not :O: → b.p. grows with DDT 0:0 0: DD ? not H3C H3C" H. CH2 CH3 :CI-Cl: DD ? not N: 0- H3Ċ :Ci-F: DD ? not N H3C -40- O H3C-CI: CH3 H, D :I-F: DD? not :0: DD ? not 0. 2. 4 :ZEU-C
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