Select the reagents that would promote the following transformation most efficiently. A 1. NaOH (excess) 2) EtBr 1. MEOH (excess) 2) EtMgBr 3) HCI В 1. t-BuONa 2) mCPBA 3) EtMgBr 4) HCI C 1. t-BuONa 2) BH3 'THF 3) H2 O2, NaOH 4) MeBr 1. NaOH (excess) 2) EtMgBr 3) HCI
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- Please label all the steps and reagents with their corresponding letter. Thanks!Which reactions will proceed faster in a polar, aprotic solvent? (CH3)2CHCH2I+Na+N3−(CH3)2CHCH2I+Na+N3− (CH3)3CBr+HSCH2CH3(CH3)3CBr+HSCH2CH3 CH3CH2CH2Br+Na+CN−CH3CH2CH2Br+Na+CN− (CH3)2CHOSO2CH3+HOCH(CH3)21. Which of the following is the strongest nucleophile? Refer to the diagram below with an MeOH, MeSH, etc. 2. Which of the following is true about the stereochemistry of SN1 reaction?a.retention of configuration at the electrophilic centerb.50:50 mixture of retention and inversion of configuration at the electrophilic centerc.inversion of configuration at the electrophilic centerd. slightly more inversion than retention at the electrophilic center
- Which of these is the best reagent to affect the transformation?For which reaction mechanisms—SN1, SN2, E1, or E2—of thefollowing statement true? A statement may be true for one or moremechanisms. Tertiary (3°) alkyl halides react faster than 2° or 1° alkyl halides.What is the major product after aqueous work up?
- Draw the products and necessary reagents of the three step retrosynthetic reaction sequence shown below. Use wedge and dash bonds to indicate stereochemistry where appropriate. Ignore inorganic byproducts. Please choose from the following options for each of the reagents. (top reagents options) A. HNO3, cat. H2SO4 B. SO3, cat. H2SO4 C. CH3C(=O)Cl, AlCl3 D. Cl2, FeCl3 E. H2O, HCl (reagents option to the right) (top reagents options) A. HNO3, cat. H2SO4 B. SO3, cat. H2SO4 C. CH3C(=O)Cl, AlCl3 D. Cl2, FeCl3 E. H2O, HCl1. Draw a reasonable arrow-pushing mechanism for the transformation shown along. 2. Identify nucleophiles and electrophiles 3. Name any type of reactions taking place like E2 or E1 4. Account for any regio- or stereoselectivityWhat is the best way to remeber the differences between Sn1, Sn2, E1 and E2 reations?
- A student wanted to know whether the greater proximity of the ucleophile to the C-2 carbon in the transition state is what causes the 1,2-addition product to be formed faster when 1,3-butadiene reacts with HCl. Therefore, she decided to investigate the reaction of 2-methyl-1,3-cyclohexadiene with HCl.Her friend told her that she should use 1-methyl-1,3-cyclohexadiene instead. Should she follow her friend’s advice?Supply the missing reagent in the following reaction: (see attachment) A. Lindlar, H2, mCPBA B. O3 or KMnO4 C. fused KOH D. NH3 E. NaNH2Draw the molecule: Under second-order conditions (strong base/nucleophile), SN2 and E2 reactions may occur simultaneously and compete with each other.Show what products might be expected from the reaction of 2-bromo-3-methylbutane (a moderately hindered 2∘∘ alkyl halide) with sodium ethoxide. Do not worry about sterechemistry inther SN2 product for this problem. Don't forget about stereochemistry.