Shown below is the structure of a potent natural anti-inflammatory agent, NPD1. Select the stater that best describes the carbon-carbon double bonds found in NPD1.
Q: Identify the most stable radical structure. II CH2 CH3 II IV H2C.
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- Which of the following chair structures represents the most stable conformation of the 1,4-dichlorocyclohexane structure shown below? A a B b C C D d E e CI CI 1,4-dichlorocyclohexane CI CI CI CI CI. B EDraw a model of ethane. Imagine rotating the C-C single bond. a. Is there a change in the relative positions of the different atoms as the C-C bond is rotated? Yes or No? b. Does the ethane molecule have more than one conformation? Yes or No?Identify the highest and lowest energy conformation. If multiple energy conformations are degenerate, choose only one. Et H. Et Et H. H. MeEt Lowest Energy Me Highest Energy Et H. Et H. Et H. H- H. MeEt Highest Energy Me Lowest Energy Et H. Me H. Me C H H H. Me MeEt Highest Energy Lowest Energy Et H. Me Me H. H H Ме MeEt Lowest Energy Highest Energy OA OB OD
- In the lowest energy conformation of the compound below, how many alkyl substituents are axial? O A. 6 B. 3 O C. 1 O D.O OE. 2Which statement is true about these conformers? H. H. H H CH3 H3C H. H,C H,C H. H. A O A and B are equally stable O Difficult to predict O A more stable than B ) B more stable thanCyclohexane structures can have two chair conformations. Draw the alternate conformation of the structure shown below. Rotations of the structure are not allowed. Br CI Flip H
- All of the following conformational models are representative of 2,3-dimethylpentane. Which of these models corresponds to its S isomer? Et OA H. Me Me H. Me OB. Me H. Et Me H. Мe OC. iPr H Me Me H. H OD. Me H H H -iPr Me MacBook PrO esc #3 24 % & 3 7 8 Q W E R ecoConsider 1,2-dimethylcyclohexane.Q: Draw the two possible chair conformations for the cis isomer. Which conformation, if either, is more stable?Consider 1,2-dimethylcyclohexane.a. Draw structures for the cis and trans isomers using a hexagon for the six-membered ring.b. Draw the two possible chair conformations for the cis isomer. Which conformation, if either, is more stable?c. Draw the two possible chair conformations for the trans isomer. Which conformation, if either, is more stable?d. Which isomer, cis or trans, is more stable and why?
- Model 2. Cyclohexane Chair Conformation Another helpful way to drawn a non-planar example of cyclohexane is to draw its most stable (lowest energy) conformation called a chair conformation. III 8. Build two models of cyclohexane. The chair conformation is the most stable conformation of cyclohexane because all of the bond angles around the carbon atoms are at 109.5ª and all carbon atoms are in the more stable staggered conformation. Cyclohexane is the only cyclic structure that allows all the bond angles around each carbon to be 109.5", thus is the only ring that adopts a true chair conformation. Form the chair conformation with both of your cyclohexane models. Look down each carbon carbon bond and verify that all carbons are in a staggered conformation. 9. 10. Because of this conformation, there are two types of positions a group can occupy when it is attached to a cyclohexane chair, either axial (A) or equatorial (E). 11. Axial hydrogens alternate straight up and straight down as we…88 5. Draw the following molecules in two difference configurations about the double bond. Name the molecules and be sure to include the appropriate configuration (trans or cis). If the structure cannot be drawn in two different configurations, explain why. a. Н2С-СН2 b. CH3CH=CHCH3 c. Cl(CH3)C=CHCH3Which of the following is the staggered conformation for rotation about the C1- C2 bond in the following structure? HyCH;C H. CH H3C. H,C H. H,C H,CH C. H