(structure below) is proposed as amodel compound for an application of theparticle-in-a-ring model. Assume C-C R, tobe 1.5 Å."/~Calculate the wavelength (in nm) of thelowest-energy electronic transition (HOMOto the LUMO)

Answered: Image /qna-images/answer/0137e0d2-a275-410a-867e-093d327f1362.jpg

(structure below) is proposed as a model compound for an application of the particle-in-a-ring model. Assume C-C R, to be 1.5 Å. IN V Calculate the wavelength (in nm) of the lowest-energy electronic transition (HOMO to the LUMO)

(structure below) is proposed as a model compound for an application of the particle-in-a-ring model. Assume C-C R, to be 1.5 Å. IN V Calculate the wavelength (in nm) of the lowest-energy electronic transition (HOMO to the LUMO)

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter15: Introduction To Electronic Spectroscopy And Structure

Section: Chapter Questions

Problem 15.69E

See similar textbooks

Related questions

Q: Chemistry formulae of p and s at their lowest oxidation state

A: The oxidation state of an element in a compound is indicated by its oxidation number. The three…

Q: For the Reaction Scheme below provide the following (i) list all the reagents and conditions needed…

A: Here we have to synthesize the following given target compound from the given starting material…

Q: nd the pH of the solution when 0.0200 M an amino acid (NH: "RCOO) is titrated to the equivalence…

A: find the pH of the solution

Q: Which compounds contain stereocentres? I. III. Select one: II, IV a. O b. I, II О с. I, III O d.…

A: Stereocenter, a Carbon center having 4 different groups is Stereocenter.

Q: EXAMPLE 8-4 Calculating the Wavelength of a Line in the Hydrogen Spectrum Determine the wavelength…

A: The emission spectrum of the atomic hydrogen atom has been divided into a number of spectral series,…

Q: Question 36 41 Listen ➤ Determine a limiting reagent in the following reaction. What is the…

Q: Using the electronegativity values from the equation bank, show the determination of the polarity of…

A: Electronegativity is defined as the property of atoms to attract electron pairs towards itself, in a…

Q: Estimate the molar volume of CO2 at 500K and 100 atm by treating it as a van der Waals gas. The van…

A: Find an expression for the molar volume by solving the vander wall equation:

Q: H₂C COOH COOH IV, I, III, II IV, II, III, I II, III, I, IV I, III, II, IV COOH CH3COOH NO₂ I II III…

Q: Show the calculation of the volume of H₂O gas formed by the combustion of 18.6 grams of C6H6 at 30°C…

A: Given: Mass of benzene = 18.6 g Pressure = 1.10 atm Temperature = 30oC = 273+30K=303 K Known: Molar…

Q: Explain briefly the types of coal and draw a diagram.

A: COAL : The sedimentary rock known as coal is blackish or brownish-black in colour and formed from…

Q: What are the functional groups and metabolic I pathway for the Nabumetone (with name of phase I…

A: FUNCTIONAL GROUP AND METABOLIC I PATHWAY FOR THE NABUMETONE

Q: ta The solubility of KNO3 is 30 g/100 g H₂O at 20 °C. If you mixed 95 g of KNO3 in 300 g of water,…

Q: In the potentiometric standardization of a K2Cr2O7 solution, 0.4548 g of Mohr's salt [Fe(NH4)2(SO4)2…

Q: the following, which compound has the highest boiling point? a. Hexanoic acid b. 1-Hexanol c.…

Q: Perform the following conversion of pressure units: 7,6×10 Pa = 1 atm = 760 mmHg = 760 torr = 14 =…

A: Given, Perform the following conversion of pressure units: 7.6 × 109 Pa = _____ atm Note: 1 atm =…

Q: A chemist designs a galvanic cell that uses these two half-reactions: half-reaction Cro (aq) +…

Q: Butanal (CH3CH₂CH₂CHO) reacts with (R)-1,2-propanediol (HO-CH₂CH₂CH2-OH) in the presence of an acid…

Q: Given the standard of the Cu2+/Cu and the Cu+/Cu couples are +0.340 V and +0.522 V, respectively,…

A: Given that E°Cu2+/Cu = +0.340 V E°Cu+/Cu = +0.522 V

Q: Consider the alkane, n-propane. What is the hybridization of the 3 carbon atoms? O the carbon atoms…

Q: The above compound has a boiling point than pertan-1-of because it lacks

A: Hydrogen bonding: it can also be defined as the electrostatic force of attraction between hydrogen…

Q: Which of the following represents a similarity between the ß-oxidation pathway and the biosynthesis…

Q: Draw structural condensed for all of the constitutional C6H14. structures isomers of

A: The molecular formula is C6H14 therefore, the given compound is hydrocarbon and does not have any…

Q: A medical technician is working with the four samples of radionuclides listed in the table below.…

A: Given :

Q: A block of wood measures 8.0 in high, 2.0 in wide, and 1.5 in deep. a. Name one physical property…

A: GIVEN Height of block of wood a =8.0 Width of block of wood b =2.0 length of block of wood c =1.5

Q: how can we classify softdrinks if its organic or inorganic compounds?

A: Ionic bonds are created between the atoms of molecules in inorganic substances. Organic substances…

Q: A(OH)3 (s) ⇒ A³+ (aq) + 3OH¯(aq) When a 10.0 mL sample of a saturated solution of this salt was…

Q: Describe gasfication

A: GASIFICATION:

Q: Acid rain is the result of the chemical reactions of certain pollutants in Earth’s atmosphere with…

A: Given that, Ion presented in the acid rain are H3O+ , SO42- and NO3-.

Q: (structure below) is proposed as a model compound for an application of the particle-in-a-ring…

Q: An instrument used to detect metals in drinking water can detect as little as 1 μg of mercury in 1…

A: According to this question, Using formulas are No.of atoms in V Ltrs of water = mass in V Ltrs…

Q: 2. Name each alkyne. CH3CH₂CH₂C=CH a. b. CH3CH₂CH₂C=CCH3 3. Predict the product of the following…

Q: 13. Which sets of reagents could be used to efficiently make the following amine (i) 1-butylbromide…

A: Here we have to synthesize the following given compound N,N-dimethylbutanamine from the following…

Q: What is mean by scavenger

A: Definition Simply put, scavengers are creatures that frequently eat other dead organisms and animals…

Q: mass. These include b. Calcium, magnesium, iron, and carbon c. Oxygen, calcium, iron, and nitrogen…

A: 1) (d) Oxygen, Carbon , Hydrogen , Nitrogen Since the body cannot produce these four…

Q: What is the molar concentration, millimolar (mM) concentration, and micromolar (µM) concentration…

A: moles of glycine = 3 micromoles (µmoles) = 3 x 10-6 moles volume = 6 L

Q: OH vanaf 'n piridien N-oksied. / from a pyridine N-oxide.

Q: O Identify the type of isomerism present in the complexes, [RuBr(NH3)s]CI and [RUCI(NH3)s]Br,…

A: Since, Isomerism are those phenomenon in which molecular formula is same but arrangement is…

Q: Sulfur dioxide is an air pollutant. It reacts with limestone, CaCO3(s), as shown below. 2CaCO3(s)…

Q: Propane (g) and oxygen (g) are introduced into a container at 300°C to produce carbon dioxide (g)…

A: Please find the attachment.

Q: 3. Name each compound according to the IUPAC system.

A: Dear student, since you have posted multiple questions we will…

Q: Prominent peaks for the isomeric pair shown below appear at different me values: 73, 87 and 59.…

Q: A medical technician is working with the four samples of radionuclides listed in the table below.…

A: we have to fill the given table using the concepts of radioactivity

Q: A 1.9300 g impure sample of Fe(NH4)2(SO4)2 (FW = 392.14) was dissolved in 75 mL 0.75 M H2SO4 and was…

Q: > Why is analytical chemistry a powerful tool in environmental investigation?

A: The analytical chemistry plays an important role in environmental Investigation by providing…

Q: How does Chemistry affect the Food supply, production, storage, transportation, availability,…

Q: (a) CH3CH₂-O-CH O (b) CH₂CH₂CH₂C OCH 0 (c) CH CH CH CH₂C-O-CH₂CH₂CH CH₂CH,

A: we have to name the given molecules

Q: Aluminum has a cubic closest packed structure as a solid. Assuming that aluminum has an atomic…

Q: Organic Synthesis Question! Draw the intermediate and the product. Note the regio and…

Q: Which of the following does not represent 2-methylbutane? H₂C-CH₂ CH3 CH₂ CH₂ CH₂ CH (CH₂)₂ 2 C B D

A: Given,

Question

(structure below) is proposed as a
model compound for an application of the
particle-in-a-ring model. Assume C-C R, to
be 1.5 Å.
"/
~
Calculate the wavelength (in nm) of the
lowest-energy electronic transition (HOMO
to the LUMO)

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Following the pattern of Figure 6.21, work out the correlation diagram for the CN molecule, showing the relative energy levels of the atoms and the bonding and anti-bonding orbitals of the molecule. Indicate the occupation of the MOs with arrows. State the order of the bond and comment on the magnetic properties of CN.
Compute the wavelength, frequency and wavenumber of then n=4 ---> n=3 transition of Be3+
Give the ground state electron configurations of(a) Li2 (b) Be2 (c) C2 .Use the symmetry-specific nomenclature appropriate for homonuclear diatomics. Example, Sg would stand for σg. Enclose each MO in parenthesis followed by the number of electrons in that MO, e.g., the entry (1Sg)2 would represent 1σg2. Letter P then is used to represent a pair of π MO's.
The next graph is 'Graphene's Optical Absorption Graph'. Explain why strong absorption is possible in the 4.62 eV area based on the "band structure of graphene". For the answer, please type in the case of letters, not images. Thank you.
Describe the lowest excited state of an insulating solid and brieflycomment on its relevance to quantum dots
W.P. Wijesundera et al. (Phys. Rev. A 51, 278 (1995)) attempted to determine the electron configuration of the ground state of lawrencium, element 103. The two contending configurations are [Rn]5f147s27p1 and [Rn]5f146d7s2. Write down the term symbols for each of these configurations, and identify the lowest level within each configuration. Which level would be lowest according to a simple estimate of spin–orbit coupling?
One important function of atomic and ionic radius is in regulating the uptake of oxygen by haemoglobin. for the change in ionic radius that accompanies the conversion of Fe(ll) to Fe(lll) when O2 attaches t riggers a conformational change in the protein. Which do you expect to be larger: Fe2+ or Fe3+? Why?
6. Compare atomic spectroscopy with moleculer spectroscopy. Show also the electronic transitions and spectra of both methods.?
Consider the three electronic transitions in a hydrogen atomshown here, labeled A, B, and C.(a) Three electromagnetic waves, all drawn on the samescale, are also shown. Each corresponds to one of thetransitions. Which electromagnetic wave (i), (ii), or (iii),is associated with electronic transition C?
Suppose we have a molecule in C2v . Is an A2 → B2 dipole transition allowed? If so, with what polarization? Refer to the character table below to guide your thinking. 1. Yes, with x polarization.2. Yes, with y polarization.3. No, because C2v molecules are nonpolar.4. No, because there is no polarization with the right symmetry.5. It is allowed, but only in Raman processes with xz polarization.
determine the ground state term symbol for 4d75d1(ignore spin orbit coupling)
Give full explanation of answer of the question- The Hückel determinant for a 4 Carbon containing conjugated cyclic molecule has four roots as:-1.532089, -0.347296, 1.0 and 1.879385.(there are 4 π electrons). What are the ionization potential and lowest energy excitation in terms of α and β.