The addition of dimethylglyoxime, H2C4H602N2, to a solution containing nickel(Il) ion gives rise to a precipitate: Nickel dimethylglyoxime is a bulky precipitate that is inconvenient to manipulate in amounts greater than 135 mg. The amount of nickel in a type of permanent-magnet alloy ranges between 22% and 38%. Calculate the sample size that should not be exceeded when analyzing these alloys for nickel.
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The addition of dimethylglyoxime, H2C4H602N2, to a solution containing nickel(Il) ion gives rise to a precipitate: Nickel dimethylglyoxime is a bulky precipitate that is inconvenient to manipulate in amounts greater than 135 mg. The amount of nickel in a type of permanent-magnet alloy ranges between 22% and 38%. Calculate the
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- The addition of a small amount of a salt, such as (NH4)2SO4, to a solution containing a charged protein increases the solubility of the protein in water. This observation is called the salting-in effect. However, the addition of large amounts of salt can decrease the solubility of the protein to such an extent that the protein precipitates from solution. This observation is called the salting-out effect and is used widely by biochemists to isolate and purify proteins. Consider the equilibrium PXν(s) ⇋ Pν+(aq) + ν X−(aq), where Pν+ is a polycationic protein of charge ν+ and X− is its counterion. Use Le Chatelier’s principle and the physical principles behind the Debye–Hückel theory to provide a molecular interpretation for the salting-in and salting-out effects.The maximum solid solubility of carbon in ferrite occurs at 0.022 wt% C and 727 ° C, the eutectoid composition is 0.76 wt% C, the maximum solid solubility of carbon in austenite occurs at 2.14 wt% C and 1147 ° C, and the cementite composition is 6.7 wt% C. For 2122 g of a 3.2134 wt% C steel at 726 ° C, what will be the mass of carbon present as part of a compound?(a) 67.9 g(b) 74.2 g(c) 58.7 g(d) 83.5 gThe molar conductivities at infinite dilution of aqueous solutions of NH4Cl, NaCl, and NaOH are, respectively, 130, 108.6, and 216.5 S cm2 mol-1 at 18°C. The specific conductivity of a 0.01 M solution of ammonia at the same temperature is 9.6 x 10-5 [S cm-1] and the ion product of water is 0.59 x 1014. Determine: • The concentration of NH4+ ions in the ammonia solution. • The pH of the ammonia solution.
- To determine the fluoride content in an aqueous and chloride-containing preparation of ammonium fluoride, the following analysis was performed. 105.2 mg of the preparation was dissolved in 100.0 mL of water. Then a 300 mL 40 mM lead chloride solution was added, whereby all fluoride ions were precipitated out of the solution in the form of the sparingly soluble salt PbClF (s). The precipitate was separated and washed at 15 degrees with a lead fluoride chloride saturated solution and dried at 130 degrees. The precipitate weighed 651.3 mg. a) Calculate the fluoride content (as % by weight F) in the preparation.b) Determine the purity of the ammonium fluoride preparationIn an experiment to calculate the solubility product (Ksp) of barium nitrate (Ba(NO3)2), an excess amount of Ba(NO3)2 was added to 2 liters of water at 25oC until the solution is saturated. Because Ba(NO3)2 is only slightly soluble in water, the excess Ba(NO3)2 was filtered out to get a solid-free mixture. The proponents of the experiment thought about using the concept of colligative properties, specifically boiling point elevation, to determine Ksp. It was observed in their experiments that the solution boils at 100.15 K. Barium nitrate dissociates via the process: Ba(NO3)2(s) ⇄ Ba2+(aq) + 2NO?-3(?q) Ksp = [Ba2+][NO3−]2 Calculate the following if Kb,water = 0.51 K-kg/mol: a) Amount of Ba(NO3)2 dissolved in grams. Molar mass of Ba(NO3)2 = 261.3 g/mol b) Solubility product, Ksp c) Vapor pressure of the solution in kPaIn an experiment to calculate the solubility product (Ksp) of barium nitrate (Ba(NO3)2), an excess amount of Ba(NO3)2 was added to 2 liters of water at 25oC until the solution is saturated. Because Ba(NO3)2 is only slightly soluble in water, the excess Ba(NO3)2 was filtered out to get a solid-free mixture. The proponents of the experiment thought about using the concept of colligative properties, specifically boiling point elevation, to determine Ksp. It was observed in their experiments that the solution boils at 100.15 K. Barium nitrate dissociates via the process: ?a(??3)2(?) ⇄ ??2+(?q) + 2??-3(?q) ??p = [??2+][??3−]2 Calculate the following if Kb,water = 0.51 K-kg/mol: a) Amount of Ba(NO3)2 dissolved in grams. Molar mass of Ba(NO3)2 = 261.3 g/mol b) Solubility product, Ksp c) Vapor pressure of the solution in kPa
- When 2.0 g of aspirin was shaken up in a flask containing two immiscible liquids it was found that the mole fractions in the two liqu ids were 0.11 and 0.18. When a further 1.0 g of aspirin was added, it was found that the mole fraction in the first liquid increased to 0.15. What would you expect the mole fraction in the second liquid to become?What wt of magnetite should be taken for analysis in order that after converting to a precipitate of Fe2O3.xH2O, the percentage of Fe3O4 in the sample can be found by multiplying the wt in grams of the ignited precipitate (Fe2O3) by 100.The partial molar volumes of water and ethanol in a solution with xH2O=0.45 at 25 ∘C are 17.0 and 57.0 cm3⋅mol−1, respectively. Calculate the volume change upon mixing sufficient ethanol with 4.30 mol of water to give this concentration. The densities of water and ethanol are 0.997 and 0.7893 g⋅cm−3, respectively, at this temperature. Express your answer to two significant figures and include the appropriate units.
- The vapor pressures of two volatile organic compounds, compound 1 and compound 2, at 20 °C are 82.2 torr and 332.2 torr, respectively. What is the gas phase mole fraction of compound 1 above a solution containing an equimolar mixture of the two compounds?Please enter your response in standard notation to three significant figures.The following evidence was obtained from an experiment to determine the solubility of calcium chloride at room temperature. A sample of saturated calcium chloride solution was evaporated to dryness, and the mass of solid residue was measured.EvidenceVolume of solution (mL) = 15.0Mass of empty beaker (g) = 90.54Mass of beaker and residue (g) = 101.36The solubility of calcium chloride is g/100 mLA student determines the molar mass of a liquid unknown by the method used in this experiment. She found that the equilibrum temperature of a mixture of ice and water was 1.0 degrees C on her thermometer. When she added 11.1 g of her unknown sample to the mixture, the temperature, after thorough stirring, fell to -3.0 degrees C. She then poured off the solution through a screen into a beaker. The mass of the solution was 90.4 g. Kf=1.86 degrees C/m How much water was in the decanted solution? What did she find to be the molar mass of the unknown liquid, assuming she made the calculation properly?