The ascorbic acid, CH;Os (176.124 g/mmol) content of a bottle of peach juice containing 2.50 L was determined by titration with a standard solution of potassium iodate, KIO,. The KIO, solution was prepared by dissolving 100.4 mg primary standard grade KIO; (214.001 mg/mmol) to a final volume of 250.0 mL. To a 200.00-mL aliquot of the sample, 10 mL of KI, 10 mL of HCl and 5 mL of starch solution were added and subsequently titrated, requiring 18.19 mL of the KIO; titrant. The relevant reactions are given below: KIO, + 5KI + 6H* → 31; + 6K* + 3H;0 CH;O, + 12 → CH,O, + 21- + 2H a. How many millimoles of ascorbic acid is in the titrated sample? b. What is the mass of ascorbic acid per bottle of the peach juice?

Fundamentals Of Analytical Chemistry
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Chapter16: Applications Of Neutralization Titrations
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Problem 16.40QAP
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The ascorbic acid, C,H;Os (176.124 g/mmol) content of a bottle of peach juice containing 2.50 L was
determined by titration with a standard solution of potassium iodate, KIO3. The KIO; solution was
prepared by dissolving 100.4 mg primary standard grade KIO; (214.001 mg/mmol) to a final volume of
250.0 mL. To a 200.00-mL aliquot of the sample, 10 mL of KI, 10 mL of HCl and 5 mL of starch solution
were added and subsequently titrated, requiring 18.19 mL of the KIO; titrant. The relevant reactions are
given below:
KIO; + 5KI + 6H* → 3l2 + 6K* + 3H;0
CH;O, + l2→ CH,O, + 21- + 2H*
a. How many millimoles of ascorbic acid is in the titrated sample?
b. What is the mass of ascorbic acid per bottle of the peach juice?
Transcribed Image Text:The ascorbic acid, C,H;Os (176.124 g/mmol) content of a bottle of peach juice containing 2.50 L was determined by titration with a standard solution of potassium iodate, KIO3. The KIO; solution was prepared by dissolving 100.4 mg primary standard grade KIO; (214.001 mg/mmol) to a final volume of 250.0 mL. To a 200.00-mL aliquot of the sample, 10 mL of KI, 10 mL of HCl and 5 mL of starch solution were added and subsequently titrated, requiring 18.19 mL of the KIO; titrant. The relevant reactions are given below: KIO; + 5KI + 6H* → 3l2 + 6K* + 3H;0 CH;O, + l2→ CH,O, + 21- + 2H* a. How many millimoles of ascorbic acid is in the titrated sample? b. What is the mass of ascorbic acid per bottle of the peach juice?
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