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- What carbon radical is formed by homolysis of the C–Ha bond inpropylbenzene? Draw all reasonable resonance structures for thisradical.The rate of hydration of 2-butene and 2-methylpropene differ by several orders of magnitude. Whcih alkene is more rapidly hydrated and why?Which of the following statement/s is/are false about the reaction of 3-methylhex-3-ene with H3O+?
- Draw the mechanism fot his reaction. B = [IrCl(CO)(PPH3)2]Homolysis of the indicated C–H bond in propene forms a resonancestabilizedradical. Question: Use half-headed curved arrows to illustrate how one resonancestructure can be converted to the other.What is the substitution reaction mechanism used to yield 7-chloro-4-ethylhept-2-ene? Please draw it out with all steps and arrows.
- Identify each of the following species as either nucleophilic or electrophilic: Cl-, H+, and carbon in H3C+The replacement of CH3OH to dimethyl sulfoxide, DMSO (CH3)2S=O) as a solvent in the substitution reaction below results in what?What carbon radical is formed by homolysis of the C–Hb bond inpropylbenzene? Draw all reasonable resonance structures for thisradical.
- Homolysis of the indicated C–H bond in propene forms a resonancestabilizedradical. Question: Draw the two possible resonance structures for this radical.The reactants, intermediates, final products, and all curved arrows showing bonds forming andbreaking are collectively referred to as the mechanism of a reaction. For the following reactants: a. Explain why the original statement of Markovnikov’s rule does not help in this case, but themodern restatement of Markovnikov’s rule tells you which carbon will get the X (Cl). b. Show the mechanism of the most likely addition reaction between the reactants.Plastic photochromic sunglasses are based on the following reversible rearrangement of a dye inside the lenses that occurs when the lenses are exposed to sunlight. The original dye absorbs UV light but not visible light and is thus colorless, while the rearrangement product absorbs visible light and is thus darkened. (a) Show the mechanism of the rearrangement. (b) Why does the rearrangement product absorb at a longer wavelength (visible light) than the original dye (UV)?