7-8The chiral Mn complex below undergoes racemization according to theequation shown.Mn,PhMe/25 °C´PPH3´PPH3Ph3P"PhNOti/2 = 21 min.PhNONO PhRate x1/[PPh3]Propose a mechanism that is consistent with the rate being affectedinversely by the concentration of PPh;.

The reaction proceeds in two steps. The first step is the dissociation of the ligand. After the…

The chiral Mn complex below undergoes racemization according to the equation shown. 7-8 Mn + PhMe/25 °C ´PPH3 PPH3 Ph3P" NO NO NO Ph ti/2 = 21 min. Rate x 1/[PPH3] Ph Ph Propose a mechanism that is consistent with the rate being affected inversely by the concentration of PPH3.

The chiral Mn complex below undergoes racemization according to the equation shown. 7-8 Mn + PhMe/25 °C ´PPH3 PPH3 Ph3P" NO NO NO Ph ti/2 = 21 min. Rate x 1/[PPH3] Ph Ph Propose a mechanism that is consistent with the rate being affected inversely by the concentration of PPH3.

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter11: Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations

Section11.SE: Something Extra

Problem 40AP: The following Walden cycle has been carried out. Explain the results, and indicate where Walden...

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Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

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7-8
The chiral Mn complex below undergoes racemization according to the
equation shown.
Mn,
PhMe/25 °C
´PPH3
´PPH3
Ph3P"
Ph
NO
ti/2 = 21 min.
Ph
NO
NO Ph
Rate x
1/[PPh3]
Propose a mechanism that is consistent with the rate being affected
inversely by the concentration of PPh;.

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