The concentration of KClO3 in the explosive sample can be determined by reaction with Fe(II): ClO3- + 6Fe2+ + 6H+ Cl- + 3H2O + 6Fe3+. 50.00 ml of 0.08930 M Fe2+ solution was added to 0.1279 grams of explosive sample, and after the reaction, the excess Fe2+ was titrated with 0.08361 M Ce4+ solution, which consumed 14.93 ml. Calculate the KClO3 concentration of the explosive sample in percent by weight.

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter22: The Chemistry Of The Transistion Elements
Section22.6: Colors Of Coordination Compounds
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The concentration of KClO3 in the explosive sample can be determined by reaction with Fe(II):
ClO3- + 6Fe2+ + 6H+ Cl- + 3H2O + 6Fe3+. 50.00 ml of 0.08930 M Fe2+ solution was added to 0.1279 grams of explosive sample, and after the reaction, the excess Fe2+ was titrated with 0.08361 M Ce4+ solution, which consumed 14.93 ml. Calculate the KClO3 concentration of the explosive sample in percent by weight.

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