The decomposition of hydrogen peroxide is catalyzed byiodide ion. The catalyzed reaction is thought to proceedby a two-step mechanism:H2O2(aq) + I - (aq)---->H2O(l) + IO- (aq) (slow)IO- (aq) + H2O2(aq)--->H2O(l) + O2(g) + I - (aq) (fast)(a) Write the chemical equation for the overall process.(b) Identify the intermediate, if any, in the mechanism.(c) Assuming that the first step of the mechanism is ratedetermining, predict the rate law for the overall process.

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 19QAP: The decomposition of nitrogen dioxide is a second-order reaction. At 550 K, a 0.250 M sample...
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The decomposition of hydrogen peroxide is catalyzed by
iodide ion. The catalyzed reaction is thought to proceed
by a two-step mechanism:
H2O2(aq) + I - (aq)---->H2O(l) + IO- (aq) (slow)
IO- (aq) + H2O2(aq)--->H2O(l) + O2(g) + I - (aq) (fast)
(a) Write the chemical equation for the overall process.
(b) Identify the intermediate, if any, in the mechanism.
(c) Assuming that the first step of the mechanism is rate
determining, predict the rate law for the overall process.

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