In a study of the gas phase decomposition of hydrogen peroxide at 400 °C H2O2(g)H20(g) + ½ O2(g) the following data were obtained: H2O2), M 0.122 3.05x10-2 44.8 6.10x10-2 1.53x10-2 seconds 14.9 104 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 0.122 M is s and when the starting concentration is 6.10×102 M is (2) The average A(1/[H2O2]) / At from t = 0 s to t= 14.9 s is The average A(1/[H2O2])/ At from t = 14.9 s to t= 44.8 s is M's M's (3) Based on these data, the rate constant for this v order reaction is M's.

Chemistry for Engineering Students
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Chapter11: Chemical Kinetics
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In a study of the gas phase decomposition of hydrogen peroxide at 400 °C
H2O2(g)H20(g) + % O2(g)
the following data were obtained:
[H2O2], M
0.122
6.10x10-2
3.05x10-2
1.53x10-2
104
seconds
14.9
44.8
Hint: It is not necessary to graph these data.
(1)
The observed half life for this reaction when the starting concentration is 0.122 M is
s and when the starting concentration is 6.10×10-2 M is
(2)
The average A(1/[H2O2])/ At from t= 0 s to t= 14.9 s is
The average A(1/[H2O2])/ At from tD
14.9 s to t= 44.8 s is
(3)
Based on these data, the rate constant for this
order reaction is
M's.
Transcribed Image Text:In a study of the gas phase decomposition of hydrogen peroxide at 400 °C H2O2(g)H20(g) + % O2(g) the following data were obtained: [H2O2], M 0.122 6.10x10-2 3.05x10-2 1.53x10-2 104 seconds 14.9 44.8 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 0.122 M is s and when the starting concentration is 6.10×10-2 M is (2) The average A(1/[H2O2])/ At from t= 0 s to t= 14.9 s is The average A(1/[H2O2])/ At from tD 14.9 s to t= 44.8 s is (3) Based on these data, the rate constant for this order reaction is M's.
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