The distribution ratio D for an analyte is defined as the ratio of its analytical concentration in two immiscible solvents (organic versus aqueous): D = Corg/Caq Show that the fraction of analyte remained in the aqueous phase after the extraction (from aqueous to organic) is given by the following: Fraction remained = Vaq/(VorgD + Vaq) where Vaq and Vorg are the volume of water and organic solvent used in the extraction, respectively.

The distribution ratio D for an analyte is defined as the ratio of its analytical concentration in two immiscible solvents (organic versus aqueous): D = Corg/Caq Show that the fraction of analyte remained in the aqueous phase after the extraction (from aqueous to organic) is given by the following: Fraction remained = Vaq/(VorgD + Vaq) where Vaq and Vorg are the volume of water and organic solvent used in the extraction, respectively.

Appl Of Ms Excel In Analytical Chemistry

2nd Edition

ISBN:9781285686691

Author:Crouch

Publisher:Crouch

Chapter14: Chromatography

Section: Chapter Questions

Problem 9P

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Consider the titration illustrated in Figure 8.] Anhydrous sodium carbonate (Na₂CO₃) is a primary standard. When 0.364 grams of the substance is placed in a conical flask, then 20.00 cm³ of sulphuric acid (H₂SO₄) solution is required to reach the end point of the titration. What is the concentration in mol·dm⁻³ of the sulphuric acid solution? [Give the answer to 3 decimal places. Do not type in the unit. Use a decimal point.] *
1. What is the MW of the analyte?2. What is the meq of the analyte?3. What is the weight (in grams) of the analyte?4. What will be the percentage purity of the sample if 43mL of the titrant was consumed?5. Did the sample conform to the USP requirement? Yes or No?
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Drug: C20H22ClN (Flexeril also known as iCyclobenzaprine HCl Using unit analysis, clearly show the set-ups for your calculations. You wish to prepare 50.0 mL of 2.30 x 10–2 M solution of your drug. (hint-how many grams will you need of your drug?) Describe how to prepare this solution from the pure drug and deionized water. Analytical balances and volumetric flasks are available to you. (Assume that your drug dissolves in water, at least to the extent necessary for this problem.) Use complete sentences in your description of the solution preparation process. A patient is given 2.0mL of a 3.00% (m/v) solution of your drug, how many milligrams of the drug did they receive? What is the molarity of a 3.00% (m/v) solution of your drug?
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1) How many milliliters of 70% ethanol and 20% ethanol must be mixed to prepare 500ml of 30% ethanol? 2) A gaseous blend of nitric oxide and nitrogen (NOmax) contains 0.09% v/v nitric oxide (NO) and 99.92% v/v nitrogen. Express the strength of nitric oxide in PPM (round to whole number) 3) The ratio strength of a 10mL vial of neostigmine methylsulfate injection USP is 1:1500.Calculate the amount of neostigmine methylsulfate in milligrams contained in the 10mL vial. (Round to the whole number).
A solution of potassium phosphate contains a mixture of 164 mg of monobasic potassium phosphate (MWt: 136) and 158 mg of dibasic potassium phosphate (MWt: 174) per milliliter. If a hyperalimentation fluid calls for the addition of 45 mEq of potassium, how many milliliters of the solution should be used to provide this level of potassium? How many millimoles of total phosphate will be represented in the calculated volume of potassium phosphate solution?
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