The efficiency of a particular catalyst is highly dependent on its zirconium content. The starting material for this preparation is received in batches that assay between 68% and 84% ZrCl4. Routine analysis based on precipitation of AgCl is feasible, it having been established that there are no sources of chloride ion other than the ZrCl4 in the sample. What sample mass should be taken to ensure an AgCl precipitate that weighs at least 0.372 g? Mass of the sample =______ g If this sample mass is used, what is the maximum mass of AgCl that can be expected in this analysis? Mass of AgCl  = _______  g

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter12: Gravimetric Methods Of Analysis
Section: Chapter Questions
Problem 12.26QAP
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The efficiency of a particular catalyst is highly dependent on its zirconium content. The starting material for this preparation is received in batches that assay between 68% and 84% ZrCl4. Routine analysis based on precipitation of AgCl is feasible, it having been established that there are no sources of chloride ion other than the ZrCl4 in the sample.

  1. What sample mass should be taken to ensure an AgCl precipitate that weighs at least 0.372 g?

    Mass of the sample =______ g

  2. If this sample mass is used, what is the maximum mass of AgCl that can be expected in this analysis?

    Mass of AgCl  = _______  g

  3. To simplify calculations, what sample mass should be taken to have the percentage of ZrCl4 exceed the mass of AgCl produced by a factor of 100?

    Mass of the sample =  _______ g

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