The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: AsO33- + 2 Ce4+ + H2OAsO43- + 2 Ce3+ + 2 H+ Experiment [AsO33-]o, M [Ce4+]o, M Initial Rate, M s-1 1 3.04×10-2 0.362 2.02×10-3 2 6.08×10-2 0.362 4.03×10-3 3 3.04×10-2 0.725 8.09×10-3 4 6.08×10-2 0.725 1.62×10-2 Complete the rate law for this reaction in the box below. Use the form k[A]m[B]n , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n. Rate =     From these data, the rate constant is M-2s-1.

Chemistry: The Molecular Science
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Author:John W. Moore, Conrad L. Stanitski
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Chapter11: Chemical Kinetics: Rates Of Reactions
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The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution:

AsO33- + 2 Ce4+ + H2OAsO43- + 2 Ce3+ + 2 H+


Experiment [AsO33-]o, M [Ce4+]o, M Initial Rate, M s-1
1 3.04×10-2 0.362 2.02×10-3
2 6.08×10-2 0.362 4.03×10-3
3 3.04×10-2 0.725 8.09×10-3
4 6.08×10-2 0.725 1.62×10-2




Complete the rate law for this reaction in the box below.
Use the form k[A]m[B]n , where '1' is understood for m or n and concentrations taken to the zero power do not appear. Don't enter 1 for m or n.

Rate =    



From these data, the rate constant is M-2s-1.

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