The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution: AsO33- + 2 Ce4+ + H2OAsO43- + 2 Ce3+ + 2 H+

Chemistry: The Molecular Science
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Author:John W. Moore, Conrad L. Stanitski
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Chapter11: Chemical Kinetics: Rates Of Reactions
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The following initial rate data are for the oxidation of arsenate ion by cerium(IV) ion in aqueous solution:

AsO33- + 2 Ce4+ + H2OAsO43- + 2 Ce3+ + 2 H+


Experiment [AsO33-]o, M [Ce4+]o, M Initial Rate, M s-1
1 1.26×10-2 0.541 1.90×10-3
2 2.52×10-2 0.541 3.80×10-3
3 1.26×10-2 1.08 7.57×10-3
4 2.52×10-2 1.08 1.51×10-2




Complete the rate law for this reaction in the box below.
Use the form k[A]m[B]n , where '1' is understood for m or n and concentrations taken to the zero power do not appearDon't enter 1 for m or n.

Rate =    



From these data, the rate constant is M-2s-1.

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