The hydrogen hal ides have the following fundamental vibrational wavenumbers:                                            HF        HCI        HBr          HIv/cm-1                                      4138      2992     2649       2308(a) Calculate the force constants of the hydrogen-halogen bonds. (b) Predict the fundamental vibrational wavenumbers of the deuterium hal ides.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
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Chapter14: Rotational And Vibrational Spectroscopy
Section: Chapter Questions
Problem 14.61E
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The hydrogen hal ides have the following fundamental vibrational wavenumbers:
                                            HF        HCI        HBr          HI
v/cm-1                                      4138      2992     2649       2308
(a) Calculate the force constants of the hydrogen-halogen bonds. (b) Predict the fundamental vibrational wavenumbers of the deuterium hal ides.

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