The K, for (Cu(en),1* is much larger than the one for (Cu(NH,),]2+. This difference is primarily an entropy effect. Explain why and calculate the difference between the AS values at 298 K for the complete dissociation of the two complex ions. (Hint: The value of AH is about the same for both systems.)
The K, for (Cu(en),1* is much larger than the one for (Cu(NH,),]2+. This difference is primarily an entropy effect. Explain why and calculate the difference between the AS values at 298 K for the complete dissociation of the two complex ions. (Hint: The value of AH is about the same for both systems.)
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
Problem 31P
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![The K, for (Cu(en),1* is much larger than the one for
(Cu(NH,),]2+. This difference is primarily an entropy effect.
Explain why and calculate the difference between the AS values
at 298 K for the complete dissociation of the two complex ions.
(Hint: The value of AH is about the same for both systems.)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F1bc98ca0-73c1-48ba-b40d-d6333213786b%2Fa1ca3279-c03f-4a40-b703-da28e0d14c10%2Fdgjjm2j.png&w=3840&q=75)
Transcribed Image Text:The K, for (Cu(en),1* is much larger than the one for
(Cu(NH,),]2+. This difference is primarily an entropy effect.
Explain why and calculate the difference between the AS values
at 298 K for the complete dissociation of the two complex ions.
(Hint: The value of AH is about the same for both systems.)
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